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10NO + Cd(OH)2 → Cd(NO3)2 + 4N2O + H2O2

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Reaction of nitrogen monoxide and cadmium hydroxide
10NONitrogen monoxide + Cd(OH)2Cadmium hydroxide
⟶
Cd(NO3)2Cadmium nitrate + 4N2ODinitrotgen monoxide + H2O2Hydrogen peroxide

The reaction of nitrogen monoxide and cadmium hydroxide yields cadmium nitrate, dinitrotgen monoxide, and hydrogen peroxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of nitrogen monoxide and cadmium hydroxide
10NONitrogen monoxide + Cd(OH)2Cadmium hydroxide
⟶
Cd(NO3)2Cadmium nitrate + 4N2ODinitrotgen monoxide + H2O2Hydrogen peroxide

General equation

Reaction of self redoxing species and base
Self-redoxing speciesSelf redox agent + BaseNon-redox agent
⟶
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of nitrogen monoxide and cadmium hydroxide

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NONitrogen monoxide10
–
Self redoxing
Cd(OH)2Cadmium hydroxide1
–
Base

Products

Chemical formulaNameCoefficientTypeType in general
equation
Cd(NO3)2Cadmium nitrate1
Oxidized
–
N2ODinitrotgen monoxide4
Reduced
–
H2O2Hydrogen peroxide1
–
–

Thermodynamic changes

Changes in standard condition

Reaction of nitrogen monoxide and cadmium hydroxide
10NOGas + Cd(OH)2Crystalline solidprecipitated
⟶
Cd(NO3)2Crystalline solid + 4N2OGas + H2O2Liquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−657.7–––
per 1 mol of
−65.77–––
per 1 mol of
−657.7–––
per 1 mol of
−657.7–––
−164.4–––
per 1 mol of
−657.7–––

Changes in aqueous solution (1)

Reaction of nitrogen monoxide and cadmium hydroxide
◆
ΔrG−440.2 kJ/mol
K1.32 × 1077
pK−77.12
10NOGas + Cd(OH)2Un-ionized aqueous solution
⟶
Cd(NO3)2Ionized aqueous solution + 4N2OGas + H2O2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
–−440.2––
per 1 mol of
–−44.02––
per 1 mol of
–−440.2––
per 1 mol of
–−440.2––
–−110.0––
per 1 mol of
–−440.2––

Changes in aqueous solution (2)

Reaction of nitrogen monoxide and cadmium hydroxide
10NOGas + Cd(OH)2Un-ionized aqueous solution
⟶
Cd(NO3)2Ionized aqueous solution + 4N2OAqueous solution + H2O2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
––––
per 1 mol of
––––
per 1 mol of
––––
per 1 mol of
––––
––––
per 1 mol of
––––

Changes in aqueous solution (3)

Reaction of nitrogen monoxide and cadmium hydroxide
◆
ΔrG−409.2 kJ/mol
K4.88 × 1071
pK−71.69
10NOGas + Cd(OH)2Crystalline solidprecipitated
⟶
Cd(NO3)2Ionized aqueous solution + 4N2OGas + H2O2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−695.4−409.2−961–
per 1 mol of
−69.54−40.92−96.1–
per 1 mol of
−695.4−409.2−961–
per 1 mol of
−695.4−409.2−961–
−173.8−102.3−240–
per 1 mol of
−695.4−409.2−961–

Changes in aqueous solution (4)

Reaction of nitrogen monoxide and cadmium hydroxide
10NOGas + Cd(OH)2Crystalline solidprecipitated
⟶
Cd(NO3)2Ionized aqueous solution + 4N2OAqueous solution + H2O2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−799.2–––
per 1 mol of
−79.92–––
per 1 mol of
−799.2–––
per 1 mol of
−799.2–––
−199.8–––
per 1 mol of
−799.2–––

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NO (g)90.25[1]86.55[1]210.761[1]29.844[1]
Cd(OH)2 (cr)
precipitated
-560.7[1]-473.6[1]96[1]–
Cd(OH)2 (ai)-535.89[1]-392.10[1]-94.6[1]–
Cd(OH)2 (ao)–-442.6[1]––
* (g):Gas, (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Cd(NO3)2 (cr)-456.31[1]–––
Cd(NO3)2 (ai)-490.62[1]-300.11[1]219.7[1]–
Cd(NO3)2 (cr)
2 hydrate
-1055.62[1]–––
Cd(NO3)2 (cr)
4 hydrate
-1648.96[1]–––
N2O (g)82.05[1]104.20[1]219.85[1]38.45[1]
N2O (aq)56.1[1]–––
H2O2 (l)-187.78[1]-120.35[1]109.6[1]89.1[1]
H2O2 (g)-136.31[1]-105.57[1]232.7[1]43.1[1]
H2O2 (ao)-191.17[1]-134.03[1]143.9[1]–
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (aq):Aqueous solution, (l):Liquid, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)