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12Na + 2CsClO4 → 2NaClO + 5Na2O + Cs2O

The reaction of sodium and caesium perchlorate yields sodium hypochlorite, sodium oxide, and caesium oxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and oxidizing species
Reducing speciesReducing agent + Oxidizing speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of sodium and caesium perchlorate

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NaSodium12
Reducing
Reducing
CsClO4Caesium perchlorate2
Oxidizing
Oxidizing

Products

Chemical formulaNameCoefficientTypeType in general
equation
NaClOSodium hypochlorite2
Redoxed product
Na2OSodium oxide5
Oxidized
Cs2OCaesium oxide1

Thermodynamic changes

Changes in standard condition

Reaction of sodium and caesium perchlorate
ΔrG−2181.8 kJ/mol
K1.72 × 10382
pK−382.23
12NaCrystalline solid + 2CsClO4Ionized aqueous solution
2NaClOIonized aqueous solution + 5Na2OCrystalline solid + Cs2OCrystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−2336.3−2181.8−523
per 1 mol of
−194.69−181.82−43.6
−1168.2−1090.9−262
−1168.2−1090.9−262
per 1 mol of
−467.26−436.36−105
per 1 mol of
−2336.3−2181.8−523

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na (cr)0[1]0[1]51.21[1]28.24[1]
Na (g)107.32[1]76.761[1]153.712[1]20.786[1]
CsClO4 (cr)-443.09[1]-314.26[1]175.06[1]108.28[1]
CsClO4 (ai)-387.61[1]-300.54[1]315.1[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NaClO (ai)-347.3[1]-298.7[1]100[1]
Na2O (cr)-414.22[1]-375.46[1]75.06[1]69.12[1]
Na2O (g)-35.6[1]-52.3[1]261.2[1]55.2[1]
Cs2O (cr)-345.77[1]-308.14[1]146.86[1]75.98[1]
* (ai):Ionized aqueous solution, (cr):Crystalline solid, (g):Gas

References

List of references

  1. 1