14Cu + 2KClO4 → 7Cu2O + Cl2↑ + K2O
Last updated:
- Reaction of and potassium perchlorate
The reaction of and potassium perchlorate yields copper(I) oxide, , and potassium oxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and potassium perchlorate
General equation
- Reaction of oxidizable species and oxidizing species
- Oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and potassium perchlorate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
14 | Reducing | Oxidizable | ||
KClO4 | Potassium perchlorate | 2 | Oxidizing | Oxidizing |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
Cu2O | Copper(I) oxide | 7 | Oxidized | – |
1 | Reduced | – | ||
K2O | Potassium oxide | 1 | – | – |
Thermodynamic changes
Changes in standard condition
- Reaction of and potassium perchlorate◆
ΔrG −737.9 kJ/mol K 1.88 × 10129 pK −129.27
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −676.2 | −737.9 | 203.0 | −3.8 |
−48.30 | −52.71 | 14.50 | −0.27 | |
per 1 mol of | −338.1 | −368.9 | 101.5 | −1.9 |
per 1 mol of | −96.60 | −105.4 | 29.00 | −0.54 |
−676.2 | −737.9 | 203.0 | −3.8 | |
per 1 mol of | −676.2 | −737.9 | 203.0 | −3.8 |
Changes in aqueous solution (1)
- Reaction of and potassium perchlorate◆
ΔrG −760.5 kJ/mol K 1.71 × 10133 pK −133.23
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −778.3 | −760.5 | −64.0 | – |
−55.59 | −54.32 | −4.57 | – | |
per 1 mol of | −389.1 | −380.3 | −32.0 | – |
per 1 mol of | −111.2 | −108.6 | −9.14 | – |
−778.3 | −760.5 | −64.0 | – | |
per 1 mol of | −778.3 | −760.5 | −64.0 | – |
Changes in aqueous solution (2)
- Reaction of and potassium perchlorate◆
ΔrG −753.6 kJ/mol K 1.06 × 10132 pK −132.03
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −801.7 | −753.6 | −166 | – |
−57.26 | −53.83 | −11.9 | – | |
per 1 mol of | −400.9 | −376.8 | −83.0 | – |
per 1 mol of | −114.5 | −107.7 | −23.7 | – |
−801.7 | −753.6 | −166 | – | |
per 1 mol of | −801.7 | −753.6 | −166 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(cr) | 0[1] | 0[1] | 33.150[1] | 24.435[1] |
(g) | 338.32[1] | 298.58[1] | 166.38[1] | 20.786[1] |
KClO4 (cr) | -432.75[1] | -303.09[1] | 151.0[1] | 112.38[1] |
KClO4 (ai) | -381.71[1] | -291.79[1] | 284.5[1] | – |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Cu2O (cr) | -168.6[1] | -146.0[1] | 93.14[1] | 63.64[1] |
(g) | 0[1] | 0[1] | 223.066[1] | 33.907[1] |
(ao) | -23.4[1] | 6.94[1] | 121[1] | – |
K2O (cr) | -361.5[1] | -322.1[2] | 94.1[2] | 83.7[2] |
K2O (g) | -63[1] | – | – | – |
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 33.150 J · K−1 · mol−1
- ^ Cp°, 24.435 J · K−1 · mol−1
- ^ ΔfH°, 338.32 kJ · mol−1
- ^ ΔfG°, 298.58 kJ · mol−1
- ^ S°, 166.38 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -432.75 kJ · mol−1
- ^ ΔfG°, -303.09 kJ · mol−1
- ^ S°, 151.0 J · K−1 · mol−1
- ^ Cp°, 112.38 J · K−1 · mol−1
- ^ ΔfH°, -381.71 kJ · mol−1
- ^ ΔfG°, -291.79 kJ · mol−1
- ^ S°, 284.5 J · K−1 · mol−1
- ^ ΔfH°, -168.6 kJ · mol−1
- ^ ΔfG°, -146.0 kJ · mol−1
- ^ S°, 93.14 J · K−1 · mol−1
- ^ Cp°, 63.64 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 223.066 J · K−1 · mol−1
- ^ Cp°, 33.907 J · K−1 · mol−1
- ^ ΔfH°, -23.4 kJ · mol−1
- ^ ΔfG°, 6.94 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, -361.5 kJ · mol−1
- ^ ΔfH°, -63. kJ · mol−1
- 2James G. Speight (2017)Lange's Handbook of Chemistry, 17th editionMcGraw Hill Education
- ^ ΔfG°, -322.1 kJ · mol−1 - p.280
- ^ S°, 94.1 J · K−1 · mol−1 - p.280
- ^ Cp°, 83.7 J · K−1 · mol−1 - p.280