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  3. 14FeCO3 + 2HNO3 + 43H^+ → 14Fe^3+ + N2H5^+ + 14CO2↑ + 20H2O

14FeCO3 + 2HNO3 + 43H+ → 14Fe3+ + N2H5+ + 14CO2↑ + 20H2O

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Reaction of iron(II) carbonate and nitric acid under acidic condition
14FeCO3Iron(II) carbonate + 2HNO3Nitric acid + 43H+Hydrogen ion
⟶
14Fe3+Iron(III) ion + N2H5+Hydrazinium ion + 14CO2↑Carbon dioxide + 20H2OWater

The reaction of iron(II) carbonate, nitric acid, and hydrogen ion yields iron(III) ion, hydrazinium ion, carbon dioxide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of iron(II) carbonate and nitric acid under acidic condition
14FeCO3Iron(II) carbonate + 2HNO3Nitric acid + 43H+Hydrogen ion
⟶
14Fe3+Iron(III) ion + N2H5+Hydrazinium ion + 14CO2↑Carbon dioxide + 20H2OWater

General equation

Reaction of oxidizable species and oxidizing species under acidic condition
Oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent + H+Non-redox agent
⟶
ProductOxidation product + ProductReduction product + H2ONon-redox product

Oxidation state of each atom

Reaction of iron(II) carbonate and nitric acid under acidic condition

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
FeCO3Iron(II) carbonate14
Reducing
Oxidizable
HNO3Nitric acid2
Oxidizing
Oxidizing under acidic condition
H+Hydrogen ion43
–
Hydrogen ion

Products

Chemical formulaNameCoefficientTypeType in general
equation
Fe3+Iron(III) ion14
Oxidized
–
N2H5+Hydrazinium ion1
Reduced
–
CO2Carbon dioxide14
–
–
H2OWater20
–
Water

Thermodynamic changes

Changes in standard condition (1)

Reaction of iron(II) carbonate and nitric acid under acidic condition
◆
ΔrG−691.0 kJ/mol
K1.14 × 10121
pK−121.06
14FeCO3Crystalline solidsiderite + 2HNO3Ionized aqueous solution + 43H+Un-ionized aqueous solution
⟶
14Fe3+Un-ionized aqueous solution + N2H5+Un-ionized aqueous solution + 14CO2↑Gas + 20H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−1129.5−691.0−1474–
per 1 mol of
−80.679−49.36−105.3–
per 1 mol of
−564.75−345.5−737.0–
per 1 mol of
Hydrogen ion
−26.267−16.07−34.28–
per 1 mol of
Iron(III) ion
−80.679−49.36−105.3–
per 1 mol of
Hydrazinium ion
−1129.5−691.0−1474–
per 1 mol of
−80.679−49.36−105.3–
per 1 mol of
−56.475−34.55−73.70–

Changes in standard condition (2)

Reaction of iron(II) carbonate and nitric acid under acidic condition
◆
ΔrG−573.7 kJ/mol
K3.22 × 10100
pK−100.51
14FeCO3Crystalline solidsiderite + 2HNO3Ionized aqueous solution + 43H+Un-ionized aqueous solution
⟶
14Fe3+Un-ionized aqueous solution + N2H5+Un-ionized aqueous solution + 14CO2↑Un-ionized aqueous solution + 20H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−1413.6−573.7−2820–
per 1 mol of
−100.97−40.98−201.4–
per 1 mol of
−706.80−286.9−1410–
per 1 mol of
Hydrogen ion
−32.874−13.34−65.58–
per 1 mol of
Iron(III) ion
−100.97−40.98−201.4–
per 1 mol of
Hydrazinium ion
−1413.6−573.7−2820–
per 1 mol of
−100.97−40.98−201.4–
per 1 mol of
−70.680−28.69−141.0–

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
FeCO3 (cr)
siderite
-740.57[1]-666.67[1]92.9[1]82.13[1]
HNO3 (l)-174.10[1]-80.71[1]155.60[1]109.87[1]
HNO3 (g)-135.06[1]-74.72[1]266.38[1]53.35[1]
HNO3 (ai)-207.36[1]-111.25[1]146.4[1]-86.6[1]
HNO3 (l)
1 hydrate
-473.46[1]-328.77[1]216.90[1]182.46[1]
HNO3 (l)
3 hydrate
-1056.04[1]-811.09[1]346.98[1]325.14[1]
H+ (g)1536.202[1]–––
H+ (ao)0[1]0[1]0[1]0[1]
* (cr):Crystalline solid, (l):Liquid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Fe3+ (g)5712.8[1]–––
Fe3+ (ao)-48.5[1]-4.7[1]-315.9[1]–
N2H5+ (ao)-7.5[1]82.5[1]151[1]70.3[1]
CO2 (g)-393.509[1]-394.359[1]213.74[1]37.11[1]
CO2 (ao)-413.80[1]-385.98[1]117.6[1]–
H2O (cr)––––
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (l):Liquid

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)