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16Na + 17HSCN → 15NaSCN + NaHS + (NH4)2S + 2CH4↑

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Reaction of sodium and thiocyanic acid
16NaSodium + 17HSCNThiocyanic acid
⟶
15NaSCNSodium thiocyanate + NaHSSodium hydrogensulfide + (NH4)2SAmmonium sulfide + 2CH4↑Methane

The reaction of sodium and thiocyanic acid yields sodium thiocyanate, sodium hydrogensulfide, ammonium sulfide, and methane (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of sodium and thiocyanic acid
16NaSodium + 17HSCNThiocyanic acid
⟶
15NaSCNSodium thiocyanate + NaHSSodium hydrogensulfide + (NH4)2SAmmonium sulfide + 2CH4↑Methane

General equation

Reaction of reducing species and reducible species
Reducing speciesReducing agent + Reducible speciesOxidizing agent
⟶
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of sodium and thiocyanic acid

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NaSodium16
Reducing
Reducing
HSCNThiocyanic acid17
Oxidizing
Reducible

Products

Chemical formulaNameCoefficientTypeType in general
equation
NaSCNSodium thiocyanate15
Oxidized
–
NaHSSodium hydrogensulfide1
Oxidized
–
(NH4)2SAmmonium sulfide1
–
–
CH4Methane2
Reduced
–

Thermodynamic changes

Changes in aqueous solution (1)

Reaction of sodium and thiocyanic acid
◆
ΔrG−4537.6 kJ/mol
K8.98 × 10794
pK−794.95
16NaCrystalline solid + 17HSCNIonized aqueous solution
⟶
15NaSCNIonized aqueous solution + NaHSIonized aqueous solution + (NH4)2SIonized aqueous solution + 2CH4↑Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−4393.8−4537.6483.5–
per 1 mol of
−274.61−283.6030.22–
per 1 mol of
−258.46−266.9228.44–
per 1 mol of
−292.92−302.5132.23–
−4393.8−4537.6483.5–
per 1 mol of
−4393.8−4537.6483.5–
per 1 mol of
−2196.9−2268.8241.8–

Changes in aqueous solution (2)

Reaction of sodium and thiocyanic acid
◆
ΔrG−4504.8 kJ/mol
K1.61 × 10789
pK−789.21
16NaCrystalline solid + 17HSCNIonized aqueous solution
⟶
15NaSCNIonized aqueous solution + NaHSIonized aqueous solution + (NH4)2SIonized aqueous solution + 2CH4↑Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−4422.3−4504.8278.3–
per 1 mol of
−276.39−281.5517.39–
per 1 mol of
−260.14−264.9916.37–
per 1 mol of
−294.82−300.3218.55–
−4422.3−4504.8278.3–
per 1 mol of
−4422.3−4504.8278.3–
per 1 mol of
−2211.2−2252.4139.2–

Changes in aqueous solution (3)

Reaction of sodium and thiocyanic acid
◆
ΔrG−4620.1 kJ/mol
K2.55 × 10809
pK−809.41
16NaCrystalline solid + 17HSCNUn-ionized aqueous solution
⟶
15NaSCNIonized aqueous solution + NaHSIonized aqueous solution + (NH4)2SIonized aqueous solution + 2CH4↑Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
–−4620.1––
per 1 mol of
–−288.76––
per 1 mol of
–−271.77––
per 1 mol of
–−308.01––
–−4620.1––
per 1 mol of
–−4620.1––
per 1 mol of
–−2310.1––

Changes in aqueous solution (4)

Reaction of sodium and thiocyanic acid
◆
ΔrG−4587.3 kJ/mol
K4.57 × 10803
pK−803.66
16NaCrystalline solid + 17HSCNUn-ionized aqueous solution
⟶
15NaSCNIonized aqueous solution + NaHSIonized aqueous solution + (NH4)2SIonized aqueous solution + 2CH4↑Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
–−4587.3––
per 1 mol of
–−286.71––
per 1 mol of
–−269.84––
per 1 mol of
–−305.82––
–−4587.3––
per 1 mol of
–−4587.3––
per 1 mol of
–−2293.7––

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na (cr)0[1]0[1]51.21[1]28.24[1]
Na (g)107.32[1]76.761[1]153.712[1]20.786[1]
HSCN (ai)76.44[1]92.71[1]144.3[1]-40.2[1]
HSCN (ao)–97.56[1]––
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NaSCN (cr)-170.50[1]–––
NaSCN (ai)-163.68[1]-169.18[1]203.3[1]6.3[1]
NaHS (cr)-237.23[1]–––
NaHS (ai)-257.73[1]-249.81[1]121.8[1]–
NaHS (cr)
2 hydrate
-838.47[1]–––
(NH4)2S (ai)-231.8[1]-72.6[1]212.1[1]–
CH4 (g)-74.81[1]-50.72[1]186.264[1]35.309[1]
CH4 (ao)-89.04[1]-34.33[1]83.7[1]–
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)