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NH4ClO3 + HMnO4 💧→ NH4MnO4↓ + HClO3

The reaction of ammonium chlorate and permanganic acid yields ammonium permanganate and chloric acid. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NH4ClO3Ammonium chlorate1
Lewis acid
Very soluble in water
HMnO4Permanganic acid1
Lewis base
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
NH4MnO4Ammonium permanganate1
Lewis conjugate
Slightly soluble in water
HClO3Chloric acid1
Non-redox product

Thermodynamic changes

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NH4ClO3 (ai)-236.48[1]-87.26[1]275.7[1]
HMnO4
* (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NH4MnO4
HClO3 (ai)-103.97[1]-7.95[1]162.3[1]
* (ai):Ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)