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(NH4)2S + Zn(MnO4)2 💧→ 2NH4MnO4↓ + ZnS↓

The reaction of ammonium sulfide and zinc permanganate yields ammonium permanganate and zinc sulfide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
(NH4)2SAmmonium sulfide1
Lewis acid
Very soluble in water
Zn(MnO4)2Zinc permanganate1
Lewis base
Soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
NH4MnO4Ammonium permanganate2
Lewis conjugate
Slightly soluble in water
ZnSZinc sulfide1
Lewis conjugate
Insoluble in water

Thermodynamic changes

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
(NH4)2S (ai)-231.8[1]-72.6[1]212.1[1]
Zn(MnO4)2 (ai)-251[1]
* (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NH4MnO4
ZnS (cr)-205.98[1]-201.29[1]57.7[1]46.0[1]
* (cr):Crystalline solid

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)