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BaBr2 + K2Cr2O7 ๐Ÿ’งโ†’ BaCrO4โ†“ + 2KBr + CrO3

The reaction of barium bromide and potassium dichromate yields barium chromate, potassium bromide, and chromium(VI) oxide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
BaBr2Barium bromide1
Lewis acid
Very soluble in water
K2Cr2O7Potassium dichromate1
Lewis base
Soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
BaCrO4Barium chromate1
Lewis conjugate
Insoluble in water
KBrPotassium bromide2
Non-redox product
โ€“
CrO3Chromium(VI) oxide1
Non-redox product
โ€“

Thermodynamic changes

Changes in standard condition

Reaction of barium bromide and potassium dichromate
BaBr2Crystalline solid + K2Cr2O7Crystalline solid
๐Ÿ’ง
โŸถ
BaCrO4โ†“Crystalline solid + 2KBrCrystalline solid + CrO3Crystalline solid
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’4.3โ€“โ€“โ€“
per 1 mol of
โˆ’4.3โ€“โ€“โ€“
โˆ’4.3โ€“โ€“โ€“
per 1 mol of
โˆ’4.3โ€“โ€“โ€“
per 1 mol of
โˆ’2.1โ€“โ€“โ€“
per 1 mol of
โˆ’4.3โ€“โ€“โ€“

Changes in aqueous solution

Reaction of barium bromide and potassium dichromate
BaBr2Ionized aqueous solution + K2Cr2O7Ionized aqueous solution
๐Ÿ’ง
โŸถ
BaCrO4โ†“Crystalline solid + 2KBrIonized aqueous solution + CrO3Crystalline solid
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’7.7โ€“โ€“โ€“
per 1 mol of
โˆ’7.7โ€“โ€“โ€“
โˆ’7.7โ€“โ€“โ€“
per 1 mol of
โˆ’7.7โ€“โ€“โ€“
per 1 mol of
โˆ’3.9โ€“โ€“โ€“
per 1 mol of
โˆ’7.7โ€“โ€“โ€“

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
BaBr2 (cr)-757.3[1]-736.8[1]146[1]โ€“
BaBr2 (g)-439[1]-473[1]331[1]61.5[1]
BaBr2 (ai)-780.73[1]-768.68[1]174.5[1]โ€“
BaBr2 (cr)
1 hydrate
-1068.2[1]โ€“โ€“โ€“
BaBr2 (cr)
2 hydrate
-1366.1[1]-1230.4[1]226[1]โ€“
K2Cr2O7 (cr)-2061.5[1]-1881.8[1]291.2[1]219.24[1]
K2Cr2O7 (ai)-1994.9[1]-1867.6[1]466.9[1]โ€“
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
BaCrO4 (cr)-1446.0[1]-1345.22[1]158.6[1]โ€“
KBr (cr)-393.798[1]-380.66[1]95.90[1]52.30[1]
KBr (g)-180.08[1]-212.96[1]250.52[1]36.920[1]
KBr (ai)-373.92[1]-387.23[1]184.9[1]-120.1[1]
CrO3 (cr)-589.5[1]โ€“โ€“โ€“
CrO3 (g)-385.8[1]โ€“โ€“โ€“
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)