BaBr2 + K2Cr2O7 ๐งโ BaCrO4โ + 2KBr + CrO3
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- Reaction of barium bromide and potassium dichromate
The reaction of barium bromide and potassium dichromate yields barium chromate, potassium bromide, and chromium(VI) oxide. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of barium bromide and potassium dichromate
General equation
- Precipitation reaction
- Miscible with water/Very soluble in water/Soluble in waterLewis acid + Miscible with water/Very soluble in water/Soluble in waterLewis base๐งโถ Insoluble in water/Very slightly soluble in water/Slightly soluble in waterLewis conjugate + Product(Non-redox product)
Oxidation state of each atom
- Reaction of barium bromide and potassium dichromate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
BaBr2 | Barium bromide | 1 | Lewis acid | Very soluble in water |
K2Cr2O7 | Potassium dichromate | 1 | Lewis base | Soluble in water |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
BaCrO4 | Barium chromate | 1 | Lewis conjugate | Insoluble in water |
KBr | Potassium bromide | 2 | Non-redox product | โ |
CrO3 | Chromium(VI) oxide | 1 | Non-redox product | โ |
Thermodynamic changes
Changes in standard condition
- Reaction of barium bromide and potassium dichromate
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ4.3 | โ | โ | โ |
per 1 mol of | โ4.3 | โ | โ | โ |
per 1 mol of | โ4.3 | โ | โ | โ |
per 1 mol of | โ4.3 | โ | โ | โ |
per 1 mol of | โ2.1 | โ | โ | โ |
per 1 mol of | โ4.3 | โ | โ | โ |
Changes in aqueous solution
- Reaction of barium bromide and potassium dichromate
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ7.7 | โ | โ | โ |
per 1 mol of | โ7.7 | โ | โ | โ |
per 1 mol of | โ7.7 | โ | โ | โ |
per 1 mol of | โ7.7 | โ | โ | โ |
per 1 mol of | โ3.9 | โ | โ | โ |
per 1 mol of | โ7.7 | โ | โ | โ |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
---|---|---|---|---|
BaBr2 (cr) | -757.3[1] | -736.8[1] | 146[1] | โ |
BaBr2 (g) | -439[1] | -473[1] | 331[1] | 61.5[1] |
BaBr2 (ai) | -780.73[1] | -768.68[1] | 174.5[1] | โ |
BaBr2 (cr) 1 hydrate | -1068.2[1] | โ | โ | โ |
BaBr2 (cr) 2 hydrate | -1366.1[1] | -1230.4[1] | 226[1] | โ |
K2Cr2O7 (cr) | -2061.5[1] | -1881.8[1] | 291.2[1] | 219.24[1] |
K2Cr2O7 (ai) | -1994.9[1] | -1867.6[1] | 466.9[1] | โ |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
---|---|---|---|---|
BaCrO4 (cr) | -1446.0[1] | -1345.22[1] | 158.6[1] | โ |
KBr (cr) | -393.798[1] | -380.66[1] | 95.90[1] | 52.30[1] |
KBr (g) | -180.08[1] | -212.96[1] | 250.52[1] | 36.920[1] |
KBr (ai) | -373.92[1] | -387.23[1] | 184.9[1] | -120.1[1] |
CrO3 (cr) | -589.5[1] | โ | โ | โ |
CrO3 (g) | -385.8[1] | โ | โ | โ |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ฮfHยฐ, -757.3 kJ ยท molโ1
- ^ ฮfGยฐ, -736.8 kJ ยท molโ1
- ^ Sยฐ, 146. J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -439. kJ ยท molโ1
- ^ ฮfGยฐ, -473. kJ ยท molโ1
- ^ Sยฐ, 331. J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 61.5 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -780.73 kJ ยท molโ1
- ^ ฮfGยฐ, -768.68 kJ ยท molโ1
- ^ Sยฐ, 174.5 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1068.2 kJ ยท molโ1
- ^ ฮfHยฐ, -1366.1 kJ ยท molโ1
- ^ ฮfGยฐ, -1230.4 kJ ยท molโ1
- ^ Sยฐ, 226. J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -2061.5 kJ ยท molโ1
- ^ ฮfGยฐ, -1881.8 kJ ยท molโ1
- ^ Sยฐ, 291.2 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 219.24 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1994.9 kJ ยท molโ1
- ^ ฮfGยฐ, -1867.6 kJ ยท molโ1
- ^ Sยฐ, 466.9 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1446.0 kJ ยท molโ1
- ^ ฮfGยฐ, -1345.22 kJ ยท molโ1
- ^ Sยฐ, 158.6 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -393.798 kJ ยท molโ1
- ^ ฮfGยฐ, -380.66 kJ ยท molโ1
- ^ Sยฐ, 95.90 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 52.30 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -180.08 kJ ยท molโ1
- ^ ฮfGยฐ, -212.96 kJ ยท molโ1
- ^ Sยฐ, 250.52 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 36.920 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -373.92 kJ ยท molโ1
- ^ ฮfGยฐ, -387.23 kJ ยท molโ1
- ^ Sยฐ, 184.9 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, -120.1 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -589.5 kJ ยท molโ1
- ^ ฮfHยฐ, -385.8 kJ ยท molโ1