BaI2 + Na2S2O3 ๐งโ BaS2O3โ + 2NaI
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- Reaction of barium iodide and sodium thiosulfate
The reaction of barium iodide and sodium thiosulfate yields barium thiosulfate and sodium iodide. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of barium iodide and sodium thiosulfate
General equation
- Precipitation reaction
- Miscible with water/Very soluble in water/Soluble in waterLewis acid + Miscible with water/Very soluble in water/Soluble in waterLewis base๐งโถ Insoluble in water/Very slightly soluble in water/Slightly soluble in waterLewis conjugate + Product(Non-redox product)
Oxidation state of each atom
- Reaction of barium iodide and sodium thiosulfate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
BaI2 | Barium iodide | 1 | Lewis acid | Very soluble in water |
Na2S2O3 | Sodium thiosulfate | 1 | Lewis base | Very soluble in water |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
BaS2O3 | Barium thiosulfate | 1 | Lewis conjugate | Slightly soluble in water |
NaI | Sodium iodide | 2 | Non-redox product | โ |
Thermodynamic changes
Changes in standard condition
- Reaction of barium iodide and sodium thiosulfate
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ | โ | โ | โ |
per 1 mol of | โ | โ | โ | โ |
per 1 mol of | โ | โ | โ | โ |
per 1 mol of | โ | โ | โ | โ |
per 1 mol of | โ | โ | โ | โ |
Changes in aqueous solution
- Reaction of barium iodide and sodium thiosulfate
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ | โ | โ | โ |
per 1 mol of | โ | โ | โ | โ |
per 1 mol of | โ | โ | โ | โ |
per 1 mol of | โ | โ | โ | โ |
per 1 mol of | โ | โ | โ | โ |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
---|---|---|---|---|
BaI2 (cr) | -602.1[1] | โ | โ | โ |
BaI2 (g) | -326[1] | -377[1] | 343[1] | 61.5[1] |
BaI2 (ai) | -648.02[1] | -663.92[1] | 232.2[1] | โ |
BaI2 (cr) 1 hydrate | -919.2[1] | โ | โ | โ |
BaI2 (cr) 2 hydrate | -1216.7[1] | โ | โ | โ |
BaI2 (cr) 2.5 hydrate | -1363.6[1] | โ | โ | โ |
BaI2 (cr) 7 hydrate | -2676.5[1] | โ | โ | โ |
Na2S2O3 (cr) | -1123.0[1] | -1028.0[1] | 155[1] | โ |
Na2S2O3 (ai) | -1132.40[1] | -1046.0[1] | 184.1[1] | โ |
Na2S2O3 (cr) 5 hydrate | -2607.93[1] | -2229.8[1] | 372[1] | โ |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
---|---|---|---|---|
BaS2O3 (cr) | โ | โ | โ | 170.3[1] |
NaI (cr) | -287.78[1] | -286.06[1] | 98.53[1] | 52.09[1] |
NaI (g) | -79.5[1] | -121.0[1] | 248.978[1] | 36.65[1] |
NaI (ai) | -295.31[1] | -313.47[1] | 170.3[1] | -95.8[1] |
NaI (cr) 1 hydrate | -883.096[1] | -771.10[1] | 196.2[1] | โ |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ฮfHยฐ, -602.1 kJ ยท molโ1
- ^ ฮfHยฐ, -326. kJ ยท molโ1
- ^ ฮfGยฐ, -377. kJ ยท molโ1
- ^ Sยฐ, 343. J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 61.5 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -648.02 kJ ยท molโ1
- ^ ฮfGยฐ, -663.92 kJ ยท molโ1
- ^ Sยฐ, 232.2 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -919.2 kJ ยท molโ1
- ^ ฮfHยฐ, -1216.7 kJ ยท molโ1
- ^ ฮfHยฐ, -1363.6 kJ ยท molโ1
- ^ ฮfHยฐ, -2676.5 kJ ยท molโ1
- ^ ฮfHยฐ, -1123.0 kJ ยท molโ1
- ^ ฮfGยฐ, -1028.0 kJ ยท molโ1
- ^ Sยฐ, 155. J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1132.40 kJ ยท molโ1
- ^ ฮfGยฐ, -1046.0 kJ ยท molโ1
- ^ Sยฐ, 184.1 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -2607.93 kJ ยท molโ1
- ^ ฮfGยฐ, -2229.8 kJ ยท molโ1
- ^ Sยฐ, 372. J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 170.3 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -287.78 kJ ยท molโ1
- ^ ฮfGยฐ, -286.06 kJ ยท molโ1
- ^ Sยฐ, 98.53 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 52.09 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -79.5 kJ ยท molโ1
- ^ ฮfGยฐ, -121.0 kJ ยท molโ1
- ^ Sยฐ, 248.978 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 36.65 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -295.31 kJ ยท molโ1
- ^ ฮfGยฐ, -313.47 kJ ยท molโ1
- ^ Sยฐ, 170.3 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, -95.8 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -883.096 kJ ยท molโ1
- ^ ฮfGยฐ, -771.10 kJ ยท molโ1
- ^ Sยฐ, 196.2 J ยท Kโ1 ยท molโ1