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BaS + K2SO3 💧→ BaSO3↓ + K2S

The reaction of barium sulfide and potassium sulfite yields barium sulfite and potassium sulfide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
BaSBarium sulfide1
Lewis acid
Soluble in water
K2SO3Potassium sulfite1
Lewis base
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
BaSO3Barium sulfite1
Lewis conjugate
Very slightly soluble in water
K2SPotassium sulfide1
Non-redox product

Thermodynamic changes

Changes in standard condition

Reaction of barium sulfide and potassium sulfite
BaSCrystalline solid + K2SO3Crystalline solid
💧
BaSO3Crystalline solid + K2SCrystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
25
per 1 mol of
25
per 1 mol of
25
per 1 mol of
25
per 1 mol of
25

Changes in aqueous solution

Reaction of barium sulfide and potassium sulfite
BaSAqueous solution + K2SO3Ionized aqueous solution
💧
BaSO3Crystalline solid + K2SIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−17.6
per 1 mol of
−17.6
per 1 mol of
−17.6
per 1 mol of
−17.6
per 1 mol of
−17.6

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
BaS (cr)-460[1]-456[1]78.2[1]49.37[1]
BaS (g)50[1]
BaS (aq)-493.3[1]
K2SO3 (cr)-1125.5[1]
K2SO3 (ai)-1140.1[1]-1053.1[1]176[1]
* (cr):Crystalline solid, (g):Gas, (aq):Aqueous solution, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
BaSO3 (cr)-1179.5[1]
K2S (cr)-380.7[1]-364.0[1]105[1]
K2S (ai)-471.5[1]-480.7[1]190.4[1]
K2S (cr)
2 hydrate
-975.3[1]
K2S (cr)
5 hydrate
-1871.5[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution

References

List of references

  1. 1