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Ca(CH3COO)2 + 2NH4F 💧→ CaF2↓ + 2CH3COONH4

The reaction of calcium acetate and ammonium fluoride yields calcium fluoride and ammonium acetate. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Ca(CH3COO)2Calcium acetate1
Lewis acid
Very soluble in water
NH4FAmmonium fluoride2
Lewis base
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
CaF2Calcium fluoride1
Lewis conjugate
Insoluble in water
CH3COONH4Ammonium acetate2
Non-redox product

Thermodynamic changes

Changes in standard condition

Reaction of calcium acetate and ammonium fluoride
Ca(CH3COO)2Crystalline solid + 2NH4FCrystalline solid
💧
CaF2Crystalline solid + 2CH3COONH4Crystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−44.5
per 1 mol of
−44.5
per 1 mol of
−22.3
per 1 mol of
−44.5
per 1 mol of
−22.3

Changes in aqueous solution

Reaction of calcium acetate and ammonium fluoride
ΔrG−56.2 kJ/mol
K7.01 × 109
pK−9.85
Ca(CH3COO)2Ionized aqueous solution + 2NH4FIonized aqueous solution
💧
CaF2Crystalline solid + 2CH3COONH4Ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−11.5−56.2149.6
per 1 mol of
−11.5−56.2149.6
per 1 mol of
−5.75−28.174.80
per 1 mol of
−11.5−56.2149.6
per 1 mol of
−5.75−28.174.80

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Ca(CH3COO)2 (cr)-1479.5[1]
Ca(CH3COO)2 (ai)-1514.86[1]-1292.19[1]120.1[1]
Ca(CH3COO)2 (cr)
1 hydrate
-1772.3[1]
NH4F (cr)-463.96[1]-348.68[1]71.96[1]65.27[1]
NH4F (ai)-465.14[1]-358.09[1]99.6[1]-26.8[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CaF2 (cr)-1219.6[1]-1167.3[1]68.87[1]67.03[1]
CaF2 (g)-781.6[1]-790.4[1]274.37[1]51.25[1]
CaF2 (ai)-1208.09[1]-1111.15[1]-80.8[1]
CH3COONH4 (cr)-616.14[1]
CH3COONH4 (ai)-618.52[1]-448.61[1]200.0[1]73.6[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1