Ca2+ + SeO42− → CaSeO4
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- Reaction of calcium ion and selenate ion
The reaction of calcium ion and selenate ion yields calcium selenate. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of calcium ion and selenate ion
General equation
- Reaction of cation and anion
- CationLewis acid + AnionLewis base ⟶ ProductLewis conjugate + (H2O)
Oxidation state of each atom
- Reaction of calcium ion and selenate ion
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Ca2+ | Calcium ion | 1 | Lewis acid | Cation |
| SeO42− | Selenate ion | 1 | Lewis base | Anion |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| CaSeO4 | Calcium selenate | 1 | Lewis conjugate | – |
Thermodynamic changes
Changes in standard condition
- Reaction of calcium ion and selenate ion
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 32.1 | – | – | – |
per 1 mol of Calcium ion | 32.1 | – | – | – |
per 1 mol of Selenate ion | 32.1 | – | – | – |
per 1 mol of | 32.1 | – | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Ca2+ (g) | 1925.90[1] | – | – | – |
| Ca2+ (ao) | -542.83[1] | -553.58[1] | -53.1[1] | – |
| SeO42− (ao) | -599.1[1] | -441.3[1] | 54.0[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| CaSeO4 (cr) | -1109.81[1] | – | – | – |
| CaSeO4 (cr) 2 hydrate | -1706.7[1] | -1486.8[1] | 222[1] | – |
* (cr):Crystalline solid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)