You-iggy

Ca + 2HCN → Ca(CN)2 + H2

The reaction of calcium and hydrogen cyanide yields calcium cyanide and hydrogen. This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and reducible species
Reducing speciesReducing agent + Reducible speciesOxidizing agent
ProductOxidation product + ProductReduction product
Reaction of active metal and acid
Active metalReducing agent + AcidOxidizing agent
SaltOxidation product + H2Reduction product

Oxidation state of each atom

Reaction of calcium and hydrogen cyanide

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
CaCalcium1
Reducing
Reducing
Active metal
HCNHydrogen cyanide2
Oxidizing
Reducible
Acid

Products

Chemical formulaNameCoefficientTypeType in general
equation
Ca(CN)2Calcium cyanide1
Oxidized
Salt
H2Hydrogen1
Reduced
Hydrogen

Thermodynamic changes

Changes in standard condition

Reaction of calcium and hydrogen cyanide
CaCrystalline solidα + 2HCNLiquid
Ca(CN)2Crystalline solid + H2Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−402.2
per 1 mol of
−402.2
per 1 mol of
−201.1
per 1 mol of
−402.2
per 1 mol of
−402.2

Changes in aqueous solution (1)

Reaction of calcium and hydrogen cyanide
CaCrystalline solidα + 2HCNIonized aqueous solution
Ca(CN)2Aqueous solution + H2Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−539.3
per 1 mol of
−539.3
per 1 mol of
−269.6
per 1 mol of
−539.3
per 1 mol of
−539.3

Changes in aqueous solution (2)

Reaction of calcium and hydrogen cyanide
CaCrystalline solidα + 2HCNIonized aqueous solution
Ca(CN)2Aqueous solution + H2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−543.5
per 1 mol of
−543.5
per 1 mol of
−271.8
per 1 mol of
−543.5
per 1 mol of
−543.5

Changes in aqueous solution (3)

Reaction of calcium and hydrogen cyanide
CaCrystalline solidα + 2HCNUn-ionized aqueous solution
Ca(CN)2Aqueous solution + H2Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−452.3
per 1 mol of
−452.3
per 1 mol of
−226.2
per 1 mol of
−452.3
per 1 mol of
−452.3

Changes in aqueous solution (4)

Reaction of calcium and hydrogen cyanide
CaCrystalline solidα + 2HCNUn-ionized aqueous solution
Ca(CN)2Aqueous solution + H2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−456.5
per 1 mol of
−456.5
per 1 mol of
−228.3
per 1 mol of
−456.5
per 1 mol of
−456.5

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Ca (cr)
α
0[1]0[1]41.42[1]25.31[1]
Ca (g)178.2[1]144.3[1]154.884[1]20.786[1]
HCN (l)108.87[1]124.97[1]112.84[1]70.63[1]
HCN (g)135.1[1]124.7[1]201.78[1]35.86[1]
HCN (ai)150.6[1]172.4[1]94.1[1]
HCN (ao)107.1[1]119.7[1]124.7[1]
* (cr):Crystalline solid, (g):Gas, (l):Liquid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Ca(CN)2 (cr)-184.5[1]
Ca(CN)2 (aq)-238.1[1]
H2 (g)0[1]0[1]130.684[1]28.824[1]
H2 (ao)-4.2[1]17.6[1]577[1]
* (cr):Crystalline solid, (aq):Aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1