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CaSe + 12Fe2O3 → CaSeO4 + 8Fe3O4

The reaction of calcium selenide and iron(III) oxide yields calcium selenate and iron(II,III) oxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and reducible species
Reducing speciesReducing agent + Reducible speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
CaSeCalcium selenide1
Reducing
Reducing
Fe2O3Iron(III) oxide12
Oxidizing
Reducible

Products

Chemical formulaNameCoefficientTypeType in general
equation
CaSeO4Calcium selenate1
Oxidized
Fe3O4Iron(II,III) oxide8
Reduced

Thermodynamic changes

Changes in standard condition

Reaction of calcium selenide and iron(III) oxide
CaSeCrystalline solid + 12Fe2O3Crystalline solid
CaSeO4Crystalline solid + 8Fe3O4Crystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
201.6
per 1 mol of
201.6
per 1 mol of
16.80
per 1 mol of
201.6
per 1 mol of
25.20

Changes in aqueous solution

Reaction of calcium selenide and iron(III) oxide
CaSeCrystalline solid + 12Fe2O3Crystalline solid
CaSeO4Crystalline solid + 8Fe3O4Crystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
201.6
per 1 mol of
201.6
per 1 mol of
16.80
per 1 mol of
201.6
per 1 mol of
25.20

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CaSe (cr)-368.2[1]-363.2[1]67[1]
Fe2O3 (cr)-824.2[1]-742.2[1]87.40[1]103.85[1]
* (cr):Crystalline solid

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CaSeO4 (cr)-1109.81[1]
CaSeO4 (cr)
2 hydrate
-1706.7[1]-1486.8[1]222[1]
Fe3O4 (cr)-1118.4[1]-1015.4[1]146.4[1]143.43[1]
* (cr):Crystalline solid

References

List of references

  1. 1