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CoSO4 + BaS 💧→ CoS↓ + BaSO4

The reaction of cobalt(II) sulfate and barium sulfide yields cobalt(II) sulfide and barium sulfate. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
CoSO4Cobalt(II) sulfate1
Lewis acid
Very soluble in water
BaSBarium sulfide1
Lewis base
Soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
CoSCobalt(II) sulfide1
Lewis conjugate
Insoluble in water
BaSO4Barium sulfate1
Lewis conjugate
Insoluble in water

Thermodynamic changes

Changes in standard condition (1)

Reaction of cobalt(II) sulfate and barium sulfide
CoSO4Crystalline solid + BaSCrystalline solid
💧
CoSCrystalline solid + BaSO4Crystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−208
per 1 mol of
−208
per 1 mol of
−208
per 1 mol of
−208
per 1 mol of
−208

Changes in standard condition (2)

Reaction of cobalt(II) sulfate and barium sulfide
CoSO4Crystalline solid + BaSCrystalline solid
💧
CoSCrystalline solid + BaSO4Crystalline solidprecipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−201
per 1 mol of
−201
per 1 mol of
−201
per 1 mol of
−201
per 1 mol of
−201

Changes in aqueous solution

Reaction of cobalt(II) sulfate and barium sulfide
CoSO4Crystalline solid + BaSAqueous solution
💧
CoSCrystalline solid + BaSO4Ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
1154.1
per 1 mol of
1154.1
per 1 mol of
1154.1
per 1 mol of
1154.1
per 1 mol of
1154.1

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CoSO4 (cr)-888.3[1]-782.3[1]118.0[1]
CoSO4 (ai)-967.3[1]-799.1[1]-92[1]
CoSO4 (cr)
6 hydrate
-2683.6[1]-2235.36[1]367.61[1]353.38[1]
CoSO4 (cr)
7 hydrate
-2979.93[1]-2473.42[1]406.06[1]390.49[1]
BaS (cr)-460[1]-456[1]78.2[1]49.37[1]
BaS (g)50[1]
BaS (aq)-493.3[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (aq):Aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CoS (cr)-82.8[1]
BaSO4 (cr)-1473.2[1]-1362.2[1]132.2[1]101.75[1]
BaSO4 (cr)
precipitated
-1466.5[1]
BaSO4 (ai)-144.691[1]-1305.30[1]29.7[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution

References

List of references

  1. 1