CoSO4 + Mg(OH)2 → MgSO4 + Co(OH)2
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The reaction of cobalt(II) sulfate and magnesium hydroxide yields magnesium sulfate and cobalt(II) hydroxide. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of cobalt(II) sulfate and magnesium hydroxide
General equation
- Reaction of salt of weak base and strong base
- Salt of weak baseBrønsted acid + Strong baseBrønsted base ⟶ Salt of strong baseConjugate acid + Weak baseConjugate base + (H2O)
Oxidation state of each atom
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
CoSO4 | Cobalt(II) sulfate | 1 | Brønsted acid | Salt of weak base |
Mg(OH)2 | Magnesium hydroxide | 1 | Brønsted base | Strong base |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
MgSO4 | Magnesium sulfate | 1 | Conjugate acid | Salt of strong base |
Co(OH)2 | Cobalt(II) hydroxide | 1 | Conjugate base | Weak base |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −4.9 kJ/mol K 7.22 × 100 pK −0.86
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −4.9 | – | – |
per 1 mol of | – | −4.9 | – | – |
per 1 mol of | – | −4.9 | – | – |
per 1 mol of | – | −4.9 | – | – |
per 1 mol of | – | −4.9 | – | – |
Changes in standard condition (2)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −9.1 kJ/mol K 3.93 × 101 pK −1.59
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −11.8 | −9.1 | −11 | – |
per 1 mol of | −11.8 | −9.1 | −11 | – |
per 1 mol of | −11.8 | −9.1 | −11 | – |
per 1 mol of | −11.8 | −9.1 | −11 | – |
per 1 mol of | −11.8 | −9.1 | −11 | – |
Changes in standard condition (3)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −12.9 kJ/mol K 1.82 × 102 pK −2.26
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −12.9 | – | – |
per 1 mol of | – | −12.9 | – | – |
per 1 mol of | – | −12.9 | – | – |
per 1 mol of | – | −12.9 | – | – |
per 1 mol of | – | −12.9 | – | – |
Changes in standard condition (4)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Changes in standard condition (5)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −15.8 | – | – | – |
per 1 mol of | −15.8 | – | – | – |
per 1 mol of | −15.8 | – | – | – |
per 1 mol of | −15.8 | – | – | – |
per 1 mol of | −15.8 | – | – | – |
Changes in standard condition (6)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Changes in aqueous solution (1)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −5.4 kJ/mol K 8.83 × 100 pK −0.95
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −5.4 | – | – |
per 1 mol of | – | −5.4 | – | – |
per 1 mol of | – | −5.4 | – | – |
per 1 mol of | – | −5.4 | – | – |
per 1 mol of | – | −5.4 | – | – |
Changes in aqueous solution (2)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −33.8 kJ/mol K 8.35 × 105 pK −5.92
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −33.8 | – | – |
per 1 mol of | – | −33.8 | – | – |
per 1 mol of | – | −33.8 | – | – |
per 1 mol of | – | −33.8 | – | – |
per 1 mol of | – | −33.8 | – | – |
Changes in aqueous solution (3)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −38.0 kJ/mol K 4.54 × 106 pK −6.66
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −103.0 | −38.0 | −220 | – |
per 1 mol of | −103.0 | −38.0 | −220 | – |
per 1 mol of | −103.0 | −38.0 | −220 | – |
per 1 mol of | −103.0 | −38.0 | −220 | – |
per 1 mol of | −103.0 | −38.0 | −220 | – |
Changes in aqueous solution (4)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −41.8 kJ/mol K 2.10 × 107 pK −7.32
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −41.8 | – | – |
per 1 mol of | – | −41.8 | – | – |
per 1 mol of | – | −41.8 | – | – |
per 1 mol of | – | −41.8 | – | – |
per 1 mol of | – | −41.8 | – | – |
Changes in aqueous solution (5)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −18.1 kJ/mol K 1.48 × 103 pK −3.17
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −18.1 | – | – |
per 1 mol of | – | −18.1 | – | – |
per 1 mol of | – | −18.1 | – | – |
per 1 mol of | – | −18.1 | – | – |
per 1 mol of | – | −18.1 | – | – |
Changes in aqueous solution (6)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −46.5 kJ/mol K 1.40 × 108 pK −8.15
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −46.5 | – | – |
per 1 mol of | – | −46.5 | – | – |
per 1 mol of | – | −46.5 | – | – |
per 1 mol of | – | −46.5 | – | – |
per 1 mol of | – | −46.5 | – | – |
Changes in aqueous solution (7)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −50.7 kJ/mol K 7.63 × 108 pK −8.88
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −82.9 | −50.7 | −109 | – |
per 1 mol of | −82.9 | −50.7 | −109 | – |
per 1 mol of | −82.9 | −50.7 | −109 | – |
per 1 mol of | −82.9 | −50.7 | −109 | – |
per 1 mol of | −82.9 | −50.7 | −109 | – |
Changes in aqueous solution (8)
- Reaction of cobalt(II) sulfate and magnesium hydroxide◆
ΔrG −54.5 kJ/mol K 3.53 × 109 pK −9.55
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −54.5 | – | – |
per 1 mol of | – | −54.5 | – | – |
per 1 mol of | – | −54.5 | – | – |
per 1 mol of | – | −54.5 | – | – |
per 1 mol of | – | −54.5 | – | – |
Changes in aqueous solution (9)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Changes in aqueous solution (10)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Changes in aqueous solution (11)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −107.0 | – | – | – |
per 1 mol of | −107.0 | – | – | – |
per 1 mol of | −107.0 | – | – | – |
per 1 mol of | −107.0 | – | – | – |
per 1 mol of | −107.0 | – | – | – |
Changes in aqueous solution (12)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Changes in aqueous solution (13)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Changes in aqueous solution (14)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Changes in aqueous solution (15)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −86.9 | – | – | – |
per 1 mol of | −86.9 | – | – | – |
per 1 mol of | −86.9 | – | – | – |
per 1 mol of | −86.9 | – | – | – |
per 1 mol of | −86.9 | – | – | – |
Changes in aqueous solution (16)
- Reaction of cobalt(II) sulfate and magnesium hydroxide
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
CoSO4 (cr) | -888.3[1] | -782.3[1] | 118.0[1] | – |
CoSO4 (ai) | -967.3[1] | -799.1[1] | -92[1] | – |
CoSO4 (cr) 6 hydrate | -2683.6[1] | -2235.36[1] | 367.61[1] | 353.38[1] |
CoSO4 (cr) 7 hydrate | -2979.93[1] | -2473.42[1] | 406.06[1] | 390.49[1] |
Mg(OH)2 (cr) | -924.54[1] | -833.51[1] | 63.18[1] | 77.03[1] |
Mg(OH)2 (am) precipitated | -920.5[1] | – | – | – |
Mg(OH)2 (g) | -561[1] | – | – | – |
Mg(OH)2 (ai) | -926.84[1] | -769.4[1] | -159.4[1] | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (am):Amorphous solid, (g):Gas
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
MgSO4 (cr) | -1284.9[1] | -1170.6[1] | 91.6[1] | 96.48[1] |
MgSO4 (ai) | -1376.12[1] | -1199.5[1] | -118.0[1] | – |
MgSO4 (ao) | -1356.0[1] | -1212.21[1] | -7.1[1] | – |
MgSO4 (cr) 1 hydrate | -1602.1[1] | -1428.7[1] | 126.4[1] | – |
MgSO4 (am) 1 hydrate | -1574.9[1] | -1404.9[1] | 138.1[1] | – |
MgSO4 (cr) 2 hydrate | -1896.2[1] | – | – | – |
MgSO4 (cr) 4 hydrate | -2496.6[1] | – | – | – |
MgSO4 (cr) 6 hydrate | -3087.0[1] | -2631.8[1] | 348.1[1] | 348.11[1] |
MgSO4 (cr) 7 hydrate | -3388.71[1] | -2871.5[1] | 372[1] | – |
Co(OH)2 (cr) blue, precipitated | – | -450.1[1] | – | – |
Co(OH)2 (cr) pink, precipitated | -539.7[1] | -454.3[1] | 79[1] | – |
Co(OH)2 (cr) pink, precipitated, aged | – | -458.1[1] | – | – |
Co(OH)2 (ai) | -518.0[1] | -369.0[1] | -134[1] | – |
Co(OH)2 (ao) | – | -421.7[1] | – | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (am):Amorphous solid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -888.3 kJ · mol−1
- ^ ΔfG°, -782.3 kJ · mol−1
- ^ S°, 118.0 J · K−1 · mol−1
- ^ ΔfH°, -967.3 kJ · mol−1
- ^ ΔfG°, -799.1 kJ · mol−1
- ^ S°, -92. J · K−1 · mol−1
- ^ ΔfH°, -2683.6 kJ · mol−1
- ^ ΔfG°, -2235.36 kJ · mol−1
- ^ S°, 367.61 J · K−1 · mol−1
- ^ Cp°, 353.38 J · K−1 · mol−1
- ^ ΔfH°, -2979.93 kJ · mol−1
- ^ ΔfG°, -2473.42 kJ · mol−1
- ^ S°, 406.06 J · K−1 · mol−1
- ^ Cp°, 390.49 J · K−1 · mol−1
- ^ ΔfH°, -924.54 kJ · mol−1
- ^ ΔfG°, -833.51 kJ · mol−1
- ^ S°, 63.18 J · K−1 · mol−1
- ^ Cp°, 77.03 J · K−1 · mol−1
- ^ ΔfH°, -920.5 kJ · mol−1
- ^ ΔfH°, -561. kJ · mol−1
- ^ ΔfH°, -926.84 kJ · mol−1
- ^ ΔfG°, -769.4 kJ · mol−1
- ^ S°, -159.4 J · K−1 · mol−1
- ^ ΔfH°, -1284.9 kJ · mol−1
- ^ ΔfG°, -1170.6 kJ · mol−1
- ^ S°, 91.6 J · K−1 · mol−1
- ^ Cp°, 96.48 J · K−1 · mol−1
- ^ ΔfH°, -1376.12 kJ · mol−1
- ^ ΔfG°, -1199.5 kJ · mol−1
- ^ S°, -118.0 J · K−1 · mol−1
- ^ ΔfH°, -1356.0 kJ · mol−1
- ^ ΔfG°, -1212.21 kJ · mol−1
- ^ S°, -7.1 J · K−1 · mol−1
- ^ ΔfH°, -1602.1 kJ · mol−1
- ^ ΔfG°, -1428.7 kJ · mol−1
- ^ S°, 126.4 J · K−1 · mol−1
- ^ ΔfH°, -1574.9 kJ · mol−1
- ^ ΔfG°, -1404.9 kJ · mol−1
- ^ S°, 138.1 J · K−1 · mol−1
- ^ ΔfH°, -1896.2 kJ · mol−1
- ^ ΔfH°, -2496.6 kJ · mol−1
- ^ ΔfH°, -3087.0 kJ · mol−1
- ^ ΔfG°, -2631.8 kJ · mol−1
- ^ S°, 348.1 J · K−1 · mol−1
- ^ Cp°, 348.11 J · K−1 · mol−1
- ^ ΔfH°, -3388.71 kJ · mol−1
- ^ ΔfG°, -2871.5 kJ · mol−1
- ^ S°, 372. J · K−1 · mol−1
- ^ ΔfG°, -450.1 kJ · mol−1
- ^ ΔfH°, -539.7 kJ · mol−1
- ^ ΔfG°, -454.3 kJ · mol−1
- ^ S°, 79. J · K−1 · mol−1
- ^ ΔfG°, -458.1 kJ · mol−1
- ^ ΔfH°, -518.0 kJ · mol−1
- ^ ΔfG°, -369.0 kJ · mol−1
- ^ S°, -134. J · K−1 · mol−1
- ^ ΔfG°, -421.7 kJ · mol−1