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CoSO4 + Mg(OH)2 → MgSO4 + Co(OH)2

The reaction of cobalt(II) sulfate and magnesium hydroxide yields magnesium sulfate and cobalt(II) hydroxide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
CoSO4Cobalt(II) sulfate1
Brønsted acid
Salt of weak base
Mg(OH)2Magnesium hydroxide1
Brønsted base
Strong base

Products

Chemical formulaNameCoefficientTypeType in general
equation
MgSO4Magnesium sulfate1
Conjugate acid
Salt of strong base
Co(OH)2Cobalt(II) hydroxide1
Conjugate base
Weak base

Thermodynamic changes

Changes in standard condition (1)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−4.9 kJ/mol
K7.22 × 100
pK−0.86
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Crystalline solid + Co(OH)2Crystalline solidblue, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−4.9
per 1 mol of
−4.9
−4.9
per 1 mol of
−4.9
−4.9

Changes in standard condition (2)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−9.1 kJ/mol
K3.93 × 101
pK−1.59
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Crystalline solid + Co(OH)2Crystalline solidpink, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−11.8−9.1−11
per 1 mol of
−11.8−9.1−11
−11.8−9.1−11
per 1 mol of
−11.8−9.1−11
−11.8−9.1−11

Changes in standard condition (3)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−12.9 kJ/mol
K1.82 × 102
pK−2.26
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Crystalline solid + Co(OH)2Crystalline solidpink, precipitated, aged
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−12.9
per 1 mol of
−12.9
−12.9
per 1 mol of
−12.9
−12.9

Changes in standard condition (4)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Crystalline solid + Co(OH)2Crystalline solidblue, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in standard condition (5)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Crystalline solid + Co(OH)2Crystalline solidpink, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−15.8
per 1 mol of
−15.8
−15.8
per 1 mol of
−15.8
−15.8

Changes in standard condition (6)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Crystalline solid + Co(OH)2Crystalline solidpink, precipitated, aged
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (1)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−5.4 kJ/mol
K8.83 × 100
pK−0.95
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Ionized aqueous solution + Co(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−5.4
per 1 mol of
−5.4
−5.4
per 1 mol of
−5.4
−5.4

Changes in aqueous solution (2)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−33.8 kJ/mol
K8.35 × 105
pK−5.92
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Ionized aqueous solution + Co(OH)2Crystalline solidblue, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−33.8
per 1 mol of
−33.8
−33.8
per 1 mol of
−33.8
−33.8

Changes in aqueous solution (3)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−38.0 kJ/mol
K4.54 × 106
pK−6.66
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Ionized aqueous solution + Co(OH)2Crystalline solidpink, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−103.0−38.0−220
per 1 mol of
−103.0−38.0−220
−103.0−38.0−220
per 1 mol of
−103.0−38.0−220
−103.0−38.0−220

Changes in aqueous solution (4)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−41.8 kJ/mol
K2.10 × 107
pK−7.32
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Ionized aqueous solution + Co(OH)2Crystalline solidpink, precipitated, aged
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−41.8
per 1 mol of
−41.8
−41.8
per 1 mol of
−41.8
−41.8

Changes in aqueous solution (5)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−18.1 kJ/mol
K1.48 × 103
pK−3.17
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Un-ionized aqueous solution + Co(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−18.1
per 1 mol of
−18.1
−18.1
per 1 mol of
−18.1
−18.1

Changes in aqueous solution (6)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−46.5 kJ/mol
K1.40 × 108
pK−8.15
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Un-ionized aqueous solution + Co(OH)2Crystalline solidblue, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−46.5
per 1 mol of
−46.5
−46.5
per 1 mol of
−46.5
−46.5

Changes in aqueous solution (7)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−50.7 kJ/mol
K7.63 × 108
pK−8.88
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Un-ionized aqueous solution + Co(OH)2Crystalline solidpink, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−82.9−50.7−109
per 1 mol of
−82.9−50.7−109
−82.9−50.7−109
per 1 mol of
−82.9−50.7−109
−82.9−50.7−109

Changes in aqueous solution (8)

Reaction of cobalt(II) sulfate and magnesium hydroxide
ΔrG−54.5 kJ/mol
K3.53 × 109
pK−9.55
CoSO4Crystalline solid + Mg(OH)2Crystalline solid
MgSO4Un-ionized aqueous solution + Co(OH)2Crystalline solidpink, precipitated, aged
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−54.5
per 1 mol of
−54.5
−54.5
per 1 mol of
−54.5
−54.5

Changes in aqueous solution (9)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Ionized aqueous solution + Co(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (10)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Ionized aqueous solution + Co(OH)2Crystalline solidblue, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (11)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Ionized aqueous solution + Co(OH)2Crystalline solidpink, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−107.0
per 1 mol of
−107.0
−107.0
per 1 mol of
−107.0
−107.0

Changes in aqueous solution (12)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Ionized aqueous solution + Co(OH)2Crystalline solidpink, precipitated, aged
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (13)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Un-ionized aqueous solution + Co(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (14)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Un-ionized aqueous solution + Co(OH)2Crystalline solidblue, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (15)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Un-ionized aqueous solution + Co(OH)2Crystalline solidpink, precipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−86.9
per 1 mol of
−86.9
−86.9
per 1 mol of
−86.9
−86.9

Changes in aqueous solution (16)

Reaction of cobalt(II) sulfate and magnesium hydroxide
CoSO4Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgSO4Un-ionized aqueous solution + Co(OH)2Crystalline solidpink, precipitated, aged
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CoSO4 (cr)-888.3[1]-782.3[1]118.0[1]
CoSO4 (ai)-967.3[1]-799.1[1]-92[1]
CoSO4 (cr)
6 hydrate
-2683.6[1]-2235.36[1]367.61[1]353.38[1]
CoSO4 (cr)
7 hydrate
-2979.93[1]-2473.42[1]406.06[1]390.49[1]
Mg(OH)2 (cr)-924.54[1]-833.51[1]63.18[1]77.03[1]
Mg(OH)2 (am)
precipitated
-920.5[1]
Mg(OH)2 (g)-561[1]
Mg(OH)2 (ai)-926.84[1]-769.4[1]-159.4[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (am):Amorphous solid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
MgSO4 (cr)-1284.9[1]-1170.6[1]91.6[1]96.48[1]
MgSO4 (ai)-1376.12[1]-1199.5[1]-118.0[1]
MgSO4 (ao)-1356.0[1]-1212.21[1]-7.1[1]
MgSO4 (cr)
1 hydrate
-1602.1[1]-1428.7[1]126.4[1]
MgSO4 (am)
1 hydrate
-1574.9[1]-1404.9[1]138.1[1]
MgSO4 (cr)
2 hydrate
-1896.2[1]
MgSO4 (cr)
4 hydrate
-2496.6[1]
MgSO4 (cr)
6 hydrate
-3087.0[1]-2631.8[1]348.1[1]348.11[1]
MgSO4 (cr)
7 hydrate
-3388.71[1]-2871.5[1]372[1]
Co(OH)2 (cr)
blue, precipitated
-450.1[1]
Co(OH)2 (cr)
pink, precipitated
-539.7[1]-454.3[1]79[1]
Co(OH)2 (cr)
pink, precipitated, aged
-458.1[1]
Co(OH)2 (ai)-518.0[1]-369.0[1]-134[1]
Co(OH)2 (ao)-421.7[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (am):Amorphous solid

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)