You-iggy

H2SiO42− + H2O → H2SiO3 + 2OH

Reaction of dihydrogensilicate ion and water
H2SiO42−Dihydrogensilicate ion + H2OWater
H2SiO3Metasilicic acid + 2OHHydroxide ion

The reaction of dihydrogensilicate ion and water yields metasilicic acid and hydroxide ion (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of dihydrogensilicate ion and water
H2SiO42−Dihydrogensilicate ion + H2OWater
H2SiO3Metasilicic acid + 2OHHydroxide ion

General equation

Reaction of ion and water with generating hydroxide ion
Cation/AnionBrønsted base + H2OBrønsted acid
Proton donating ion/AcidConjugate acid + OHConjugate base

Oxidation state of each atom

Reaction of dihydrogensilicate ion and water

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
H2SiO42−Dihydrogensilicate ion1
Brønsted base
Anion
H2OWater1
Brønsted acid
Water

Products

Chemical formulaNameCoefficientTypeType in general
equation
H2SiO3Metasilicic acid1
Conjugate acid
Acid
OHHydroxide ion2
Conjugate base
Hydroxide ion

Thermodynamic changes

Changes in standard condition

Reaction of dihydrogensilicate ion and water
ΔrG20.1 kJ/mol
K0.30 × 10−3
pK3.52
H2SiO42−Un-ionized aqueous solution + H2OLiquid
H2SiO3Un-ionized aqueous solution + 2OHUn-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
33.420.144
per 1 mol of
Dihydrogensilicate ion
33.420.144
per 1 mol of
33.420.144
per 1 mol of
33.420.144
per 1 mol of
Hydroxide ion
16.710.122

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H2SiO42− (ao)-1390.406[1]-1176.893[1]-26.32[1]
H2O (cr)
H2O (l)-285.830[2]-237.129[2]69.91[2]75.291[2]
H2O (g)-241.818[2]-228.572[2]188.825[2]33.577[2]
* (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (l):Liquid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H2SiO3 (cr)-1188.7[2]-1092.4[2]134[2]
H2SiO3 (ao)-1182.8[2]-1079.4[2]109[2]
OH (g)-143.5[2]
OH (ao)-229.994[2]-157.244[2]-10.75[2]-148.5[2]
* (cr):Crystalline solid, (ao):Un-ionized aqueous solution, (g):Gas

References

List of references

  1. 1
    Colin Stuart Walker, Anraku Sohtaro, Oda Chie, Mitsui Seiichiro, Mihara Morihiro
    Thermodynamic properties of SiO2(aq), HSiO3– and SiO3-2
    Japan Atomic Energy Agency

  2. 2