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Fe3+ + 3Cl → FeCl3

Reaction of iron(III) ion and chloride ion
Fe3+Iron(III) ion + 3ClChloride ion
FeCl3Iron(III) chloride

The reaction of iron(III) ion and chloride ion yields iron(III) chloride (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of iron(III) ion and chloride ion
Fe3+Iron(III) ion + 3ClChloride ion
FeCl3Iron(III) chloride

General equation

Reaction of cation and anion
CationLewis acid + AnionLewis base
ProductLewis conjugate + (H2O)

Oxidation state of each atom

Reaction of iron(III) ion and chloride ion

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Fe3+Iron(III) ion1
Lewis acid
Cation
ClChloride ion3
Lewis base
Anion

Products

Chemical formulaNameCoefficientTypeType in general
equation
FeCl3Iron(III) chloride1
Lewis conjugate

Thermodynamic changes

Changes in standard condition (1)

Reaction of iron(III) ion and chloride ion
ΔrG−6.1 kJ/mol
K1.17 × 101
pK−1.07
Fe3+Un-ionized aqueous solution + 3ClUn-ionized aqueous solution
FeCl3Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−6.1
per 1 mol of
Iron(III) ion
−6.1
per 1 mol of
Chloride ion
−2.0
per 1 mol of
−6.1

Changes in standard condition (2)

Reaction of iron(III) ion and chloride ion
ΔrG0.1 kJ/mol
K0.96 × 100
pK0.02
Fe3+Un-ionized aqueous solution + 3ClUn-ionized aqueous solution
FeCl3Ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−0.20.10.0
per 1 mol of
Iron(III) ion
−0.200.100.0
per 1 mol of
Chloride ion
−0.0670.0330.0
per 1 mol of
−0.200.100.0

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Fe3+ (g)5712.8[1]
Fe3+ (ao)-48.5[1]-4.7[1]-315.9[1]
Cl (g)-233.13[1]
Cl (ao)-167.159[1]-131.228[1]56.5[1]-136.4[1]
* (g):Gas, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
FeCl3 (cr)-399.49[1]-334.00[1]142.3[1]96.65[1]
FeCl3 (g)-254.0[1]
FeCl3 (ai)-550.2[1]-398.3[1]-146.4[1]
FeCl3 (ao)-404.5[1]
FeCl3 (cr)
6 hydrate
-2223.8[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

References

List of references

  1. 1