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LiI + H2SO4 → LiHSO4 + HI↑

The reaction of lithium iodide and sulfuric acid yields lithium hydrogensulfate and hydrogen iodide (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
LiILithium iodide1
Brønsted base
Salt of volatile acid
H2SO4Sulfuric acid1
Brønsted acid
Nonvolatile acid

Products

Chemical formulaNameCoefficientTypeType in general
equation
LiHSO4Lithium hydrogensulfate1
Conjugate base
Salt of non volatile acid
HIHydrogen iodide1
Conjugate acid
Volatile acid

Thermodynamic changes

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
LiI (cr)-270.41[1]-270.29[1]86.78[1]51.04[1]
LiI (g)-81.09[1]-124.34[1]232.321[1]34.64[1]
LiI (ai)-333.67[1]-344.8[1]124.7[1]-73.6[1]
LiI (cr)
1 hydrate
-590.32[1]-531.3[1]123.0[1]
LiI (cr)
2 hydrate
-890.40[1]-780.2[1]184[1]
LiI (cr)
3 hydrate
-1192.15[1]-1032.13[1]250.2[1]
H2SO4 (cr)
H2SO4 (l)-813.989[1]-690.003[1]156.904[1]138.91[1]
H2SO4 (ai)-909.27[1]-744.53[1]20.1[1]-293[1]
H2SO4 (l)
1 hydrate
-1127.621[1]-950.383[1]211.54[1]214.85[1]
H2SO4 (l)
2 hydrate
-1427.100[1]-1199.650[1]276.40[1]260.83[1]
H2SO4 (l)
3 hydrate
-1720.402[1]-1443.980[1]345.39[1]318.95[1]
H2SO4 (l)
4 hydrate
-2011.199[1]-1685.863[1]414.59[1]382.21[1]
H2SO4 (l)
6.5 hydrate
-2733.256[1]-2285.734[1]587.89[1]570.28[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (l):Liquid

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
LiHSO4
HI (g)26.48[1]1.70[1]206.594[1]29.158[1]
HI (ai)-55.19[1]-51.57[1]111.3[1]-142.3[1]
* (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)