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MnCl2 + Li2S 💧→ MnS↓ + 2LiCl

The reaction of manganese(II) chloride and lithium sulfide yields manganese(II) sulfide and lithium chloride. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
MnCl2Manganese(II) chloride1
Lewis acid
Very soluble in water
Li2SLithium sulfide1
Lewis base
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
MnSManganese(II) sulfide1
Lewis conjugate
Insoluble in water
LiClLithium chloride2
Non-redox product

Thermodynamic changes

Changes in standard condition (1)

Reaction of manganese(II) chloride and lithium sulfide
MnCl2Crystalline solid + Li2SCrystalline solid
💧
MnSCrystalline solidgreen + 2LiClCrystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−108.7
−108.7
per 1 mol of
−108.7
−108.7
per 1 mol of
−54.35

Changes in standard condition (2)

Reaction of manganese(II) chloride and lithium sulfide
MnCl2Crystalline solid + Li2SCrystalline solid
💧
MnSAmorphous solidprecipitated, pink + 2LiClCrystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−108.3
−108.3
per 1 mol of
−108.3
−108.3
per 1 mol of
−54.15

Changes in aqueous solution (1)

Reaction of manganese(II) chloride and lithium sulfide
MnCl2Ionized aqueous solution + Li2SCrystalline solid
💧
MnSCrystalline solidgreen + 2LiClIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−109.0
−109.0
per 1 mol of
−109.0
−109.0
per 1 mol of
−54.50

Changes in aqueous solution (2)

Reaction of manganese(II) chloride and lithium sulfide
MnCl2Un-ionized aqueous solution + Li2SCrystalline solid
💧
MnSCrystalline solidgreen + 2LiClIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
MnCl2 (cr)-481.29[1]-440.50[1]118.24[1]72.93[1]
MnCl2 (g)-263.6[1]
MnCl2 (ai)-555.05[1]-490.8[1]38.9[1]-222[1]
MnCl2 (ao)-492.0[1]
MnCl2 (cr)
1 hydrate
-789.9[1]-696.1[1]174.1[1]
MnCl2 (cr)
2 hydrate
-1092.0[1]-942.1[1]218.8[1]
MnCl2 (cr)
4 hydrate
-1687.4[1]-1423.6[1]303.3[1]
Li2S (cr)-441.4[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
MnS (cr)
green
-214.2[1]-218.4[1]78.2[1]49.96[1]
MnS (am)
precipitated, pink
-213.8[1]
LiCl (cr)-408.61[1]-384.37[1]59.33[1]47.99[1]
LiCl (g)-195.4[1]-216.7[1]212.824[1]33.22[1]
LiCl (ai)-445.64[1]-424.58[1]69.9[1]-67.8[1]
LiCl (cr)
1 hydrate
-712.58[1]-631.80[1]102.84[1]
LiCl (cr)
2 hydrate
-1012.65[1]
LiCl (cr)
3 hydrate
-1311.3[1]
* (cr):Crystalline solid, (am):Amorphous solid, (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)