KHSO4 + 10e− → K+ + S2− + 4O2− + H−
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- Reduction of potassium hydrogensulfate
- KHSO4Potassium hydrogensulfate + 10e−ElectronK+Potassium ion + S2−Sulfide ion + 4O2−Oxide ion + H−Hydride ion⟶
Reduction of potassium hydrogensulfate yields potassium ion, sulfide ion, oxide ion, and hydride ion (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reduction of potassium hydrogensulfate
- KHSO4Potassium hydrogensulfate + 10e−ElectronK+Potassium ion + S2−Sulfide ion + 4O2−Oxide ion + H−Hydride ion⟶
General equation
- Reduction of reducible species
- ReactantOxidizing agent + e− ⟶ ProductReduction product
Oxidation state of each atom
- Reduction of potassium hydrogensulfate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| KHSO4 | Potassium hydrogensulfate | 1 | Oxidizing | – |
| e− | Electron | 10 | – | Electron |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| K+ | Potassium ion | 1 | – | – |
| S2− | Sulfide ion | 1 | Reduced | – |
| O2− | Oxide ion | 4 | – | – |
| H− | Hydride ion | 1 | Reduced | – |
Thermodynamic changes
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| KHSO4 (cr) | -1160.6[1] | -1031.3[1] | 138.1[1] | – |
| KHSO4 (ai) | -1139.72[1] | -1039.18[1] | 234.3[1] | -63[1] |
| e− | – | – | – | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| K+ (g) | 514.26[1] | – | – | – |
| K+ (ao) | -252.38[1] | -283.27[1] | 102.5[1] | 21.8[1] |
| S2− (ao) | 33.1[1] | 85.8[1] | -14.6[1] | – |
| O2− | – | – | – | – |
| H− (g) | 138.99[1] | – | – | – |
* (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -1160.6 kJ · mol−1
- ^ ΔfG°, -1031.3 kJ · mol−1
- ^ S°, 138.1 J · K−1 · mol−1
- ^ ΔfH°, -1139.72 kJ · mol−1
- ^ ΔfG°, -1039.18 kJ · mol−1
- ^ S°, 234.3 J · K−1 · mol−1
- ^ Cp°, -63. J · K−1 · mol−1
- ^ ΔfH°, 514.26 kJ · mol−1
- ^ ΔfH°, -252.38 kJ · mol−1
- ^ ΔfG°, -283.27 kJ · mol−1
- ^ S°, 102.5 J · K−1 · mol−1
- ^ Cp°, 21.8 J · K−1 · mol−1
- ^ ΔfH°, 33.1 kJ · mol−1
- ^ ΔfG°, 85.8 kJ · mol−1
- ^ S°, -14.6 J · K−1 · mol−1
- ^ ΔfH°, 138.99 kJ · mol−1