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KI + 3RbClO4 → KIO3 + 3RbClO3

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Reaction of potassium iodide and rubidium perchlorate
KIPotassium iodide + 3RbClO4Rubidium perchlorate
⟶
KIO3Potassium iodate + 3RbClO3Rubidium chlorate

The reaction of potassium iodide and rubidium perchlorate yields potassium iodate and rubidium chlorate (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of potassium iodide and rubidium perchlorate
KIPotassium iodide + 3RbClO4Rubidium perchlorate
⟶
KIO3Potassium iodate + 3RbClO3Rubidium chlorate

General equation

Reaction of oxidizable species and oxidizing species
Oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent
⟶
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of potassium iodide and rubidium perchlorate

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
KIPotassium iodide1
Reducing
Oxidizable
RbClO4Rubidium perchlorate3
Oxidizing
Oxidizing

Products

Chemical formulaNameCoefficientTypeType in general
equation
KIO3Potassium iodate1
Oxidized
–
RbClO3Rubidium chlorate3
Reduced
–

Thermodynamic changes

Changes in standard condition

Reaction of potassium iodide and rubidium perchlorate
◆
ΔrG−73.7 kJ/mol
K8.16 × 1012
pK−12.91
KICrystalline solid + 3RbClO4Crystalline solid
⟶
KIO3Crystalline solid + 3RbClO3Crystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−70.5−73.717.5–
per 1 mol of
−70.5−73.717.5–
−23.5−24.65.83–
per 1 mol of
−70.5−73.717.5–
per 1 mol of
−23.5−24.65.83–

Changes in aqueous solution

Reaction of potassium iodide and rubidium perchlorate
◆
ΔrG−74.4 kJ/mol
K1.08 × 1013
pK−13.03
KIIonized aqueous solution + 3RbClO4Ionized aqueous solution
⟶
KIO3Ionized aqueous solution + 3RbClO3Ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−90.0−74.4−51.7–
per 1 mol of
−90.0−74.4−51.7–
−30.0−24.8−17.2–
per 1 mol of
−90.0−74.4−51.7–
per 1 mol of
−30.0−24.8−17.2–

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
KI (cr)-327.900[1]-324.892[1]106.32[1]52.93[1]
KI (g)-125.5[1]-166.1[1]258.3[1]37.11[1]
KI (ai)-307.57[1]-334.85[1]213.8[1]-120.5[1]
RbClO4 (cr)-437.23[1]-306.90[1]161.1[1]–
RbClO4 (ai)-380.49[1]-292.51[1]303.3[1]–
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
KIO3 (cr)-501.37[1]-418.35[1]151.46[1]106.48[1]
KIO3 (ai)-473.6[1]-411.2[1]220.9[1]–
RbClO3 (cr)-402.9[1]-300.3[1]151.9[1]103.18[1]
RbClO3 (ai)-355.14[1]-291.85[1]283.7[1]–
* (cr):Crystalline solid, (ai):Ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)