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NaCN + HSCN → NaSCN + HCN

The reaction of sodium cyanide and thiocyanic acid yields sodium thiocyanate and hydrogen cyanide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NaCNSodium cyanide1
Brønsted base
Salt of volatile acid
HSCNThiocyanic acid1
Brønsted acid
Nonvolatile acid

Products

Chemical formulaNameCoefficientTypeType in general
equation
NaSCNSodium thiocyanate1
Conjugate base
Salt of non volatile acid
HCNHydrogen cyanide1
Conjugate acid
Volatile acid

Thermodynamic changes

Changes in aqueous solution (1)

Reaction of sodium cyanide and thiocyanic acid
ΔrG−52.7 kJ/mol
K1.71 × 109
pK−9.23
NaCNIonized aqueous solution + HSCNIonized aqueous solution
NaSCNIonized aqueous solution + HCNUn-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−43.5−52.730.6
per 1 mol of
−43.5−52.730.6
per 1 mol of
−43.5−52.730.6
per 1 mol of
−43.5−52.730.6
per 1 mol of
−43.5−52.730.6

Changes in aqueous solution (2)

Reaction of sodium cyanide and thiocyanic acid
ΔrG−57.5 kJ/mol
K1.18 × 1010
pK−10.07
NaCNIonized aqueous solution + HSCNUn-ionized aqueous solution
NaSCNIonized aqueous solution + HCNUn-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−57.5
per 1 mol of
−57.5
per 1 mol of
−57.5
per 1 mol of
−57.5
per 1 mol of
−57.5

Changes in aqueous solution (3)

Reaction of sodium cyanide and thiocyanic acid
ΔrG0.0 kJ/mol
K1.00 × 100
pK0.00
NaCNIonized aqueous solution + HSCNIonized aqueous solution
NaSCNIonized aqueous solution + HCNIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
0.00.00.0
per 1 mol of
0.00.00.0
per 1 mol of
0.00.00.0
per 1 mol of
0.00.00.0
per 1 mol of
0.00.00.0

Changes in aqueous solution (4)

Reaction of sodium cyanide and thiocyanic acid
ΔrG−4.8 kJ/mol
K6.93 × 100
pK−0.84
NaCNIonized aqueous solution + HSCNUn-ionized aqueous solution
NaSCNIonized aqueous solution + HCNIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−4.8
per 1 mol of
−4.8
per 1 mol of
−4.8
per 1 mol of
−4.8
per 1 mol of
−4.8

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NaCN (cr)
cubic
-87.49[1]-76.43[1]115.60[1]70.37[1]
NaCN (cr)
orthorhombic
-90.75[1]
NaCN (g)109[1]79.94[1]249.43[1]51.17[1]
NaCN (ai)-89.5[1]-89.5[1]153.1[1]
NaCN (cr)
1/2 hydrate
-235.77[1]
NaCN (cr)
2 hydrate
-679.77[1]
HSCN (ai)76.44[1]92.71[1]144.3[1]-40.2[1]
HSCN (ao)97.56[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NaSCN (cr)-170.50[1]
NaSCN (ai)-163.68[1]-169.18[1]203.3[1]6.3[1]
HCN (l)108.87[1]124.97[1]112.84[1]70.63[1]
HCN (g)135.1[1]124.7[1]201.78[1]35.86[1]
HCN (ai)150.6[1]172.4[1]94.1[1]
HCN (ao)107.1[1]119.7[1]124.7[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid, (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1