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NaOH → Na+ + OH

Electrolytic dissociation of sodium hydroxide
NaOHSodium hydroxide
Na+Sodium ion + OHHydroxide ion

Electrolytic dissociation of sodium hydroxide yields sodium ion and hydroxide ion. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

Electrolytic dissociation of sodium hydroxide
NaOHSodium hydroxide
Na+Sodium ion + OHHydroxide ion

General equation

Electrolytic dissociation of hydroxide base
Hydroxide baseBrønsted base
CationConjugate acid + OH

Oxidation state of each atom

Electrolytic dissociation of sodium hydroxide

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NaOHSodium hydroxide1
Brønsted base
Hydroxide base

Products

Chemical formulaNameCoefficientTypeType in general
equation
Na+Sodium ion1
Conjugate acid
Cation
OHHydroxide ion1
Hydroxide ion

Thermodynamic changes

Changes in standard condition

Electrolytic dissociation of sodium hydroxide
ΔrG−39.655 kJ/mol
K8.86 × 106
pK−6.95
NaOHCrystalline solid
Na+Un-ionized aqueous solution + OHUn-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−44.51−39.655−16.2−161.6
per 1 mol of
−44.51−39.655−16.2−161.6
per 1 mol of
Sodium ion
−44.51−39.655−16.2−161.6
per 1 mol of
Hydroxide ion
−44.51−39.655−16.2−161.6

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NaOH (cr)-425.609[1]-379.494[1]64.455[1]59.54[1]
NaOH (g)-207.1[1]-210.0[1]228.43[1]48.37[1]
NaOH (ai)-470.114[1]-419.150[1]48.1[1]-102.1[1]
NaOH (cr)
1 hydrate
-734.543[1]-629.338[1]99.50[1]90.17[1]
NaOH (l)
2 hydrate
-1019.076[1]-873.091[1]195.979[1]239.41[1]
NaOH (l)
3.5 hydrate
-1459.798[1]-1236.356[1]286.089[1]354.43[1]
NaOH (l)
4 hydrate
-1605.15[1]-1356.64[1]318.70[1]
NaOH (l)
5 hydrate
-1894.31[1]-1596.34[1]386.06[1]
NaOH (l)
7 hydrate
-2469.02[1]-2073.80[1]526.31[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (l):Liquid

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na+ (g)609.358[1]
Na+ (ao)-240.12[1]-261.905[1]59.0[1]46.4[1]
OH (g)-143.5[1]
OH (ao)-229.994[1]-157.244[1]-10.75[1]-148.5[1]
* (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)