Na2O + 2H2CO3 → 2NaHCO3 + H2O
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- Reaction of sodium oxide and carbonic acid
The reaction of sodium oxide and carbonic acid yields sodium hydrogencarbonate and water (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of sodium oxide and carbonic acid
General equation
- Reaction of basic oxide and acid
- Basic oxideBrønsted base + AcidBrønsted acid ⟶ SaltConjugate base + H2OConjugate acid
- Reaction of strongly basic oxide and weak acid
- Strongly basic oxideBrønsted base + Weak acidBrønsted acid ⟶ Salt of weak acid and strong baseConjugate base + H2OConjugate acid
Oxidation state of each atom
- Reaction of sodium oxide and carbonic acid
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Na2O | Sodium oxide | 1 | Brønsted base | Basic oxide Strongly basic oxide |
| H2CO3 | Carbonic acid | 2 | Brønsted acid | Acid Weak acid |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| NaHCO3 | Sodium hydrogencarbonate | 2 | Conjugate base | Salt Salt of weak acid and strong base |
| H2O | Water | 1 | Conjugate acid | Water |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of sodium oxide and carbonic acid◆
ΔrG −312.83 kJ/mol K 6.39 × 1054 pK −54.81
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −336.53 | −312.83 | −79.6 | – |
per 1 mol of | −336.53 | −312.83 | −79.6 | – |
per 1 mol of | −168.26 | −156.41 | −39.8 | – |
per 1 mol of | −168.26 | −156.41 | −39.8 | – |
per 1 mol of | −336.53 | −312.83 | −79.6 | – |
Changes in standard condition (2)
- Reaction of sodium oxide and carbonic acid◆
ΔrG −314.9 kJ/mol K 1.47 × 1055 pK −55.17
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −360.1 | −314.9 | −152.4 | – |
per 1 mol of | −360.1 | −314.9 | −152.4 | – |
per 1 mol of | −180.1 | −157.4 | −76.20 | – |
per 1 mol of | −180.1 | −157.4 | −76.20 | – |
per 1 mol of | −360.1 | −314.9 | −152.4 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Na2O (cr) | -414.22[1] | -375.46[1] | 75.06[1] | 69.12[1] |
| Na2O (g) | -35.6[1] | -52.3[1] | 261.2[1] | 55.2[1] |
| H2CO3 (ao) | -699.65[1] | -623.08[1] | 187.4[1] | – |
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| NaHCO3 (cr) | -950.81[1] | -851.0[1] | 101.7[1] | 87.61[1] |
| NaHCO3 (ai) | -932.11[1] | -848.66[1] | 150.2[1] | – |
| NaHCO3 (ao) | -943.9[1] | -849.7[1] | 113.8[1] | – |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (l):Liquid, (g):Gas
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -414.22 kJ · mol−1
- ^ ΔfG°, -375.46 kJ · mol−1
- ^ S°, 75.06 J · K−1 · mol−1
- ^ Cp°, 69.12 J · K−1 · mol−1
- ^ ΔfH°, -35.6 kJ · mol−1
- ^ ΔfG°, -52.3 kJ · mol−1
- ^ S°, 261.2 J · K−1 · mol−1
- ^ Cp°, 55.2 J · K−1 · mol−1
- ^ ΔfH°, -699.65 kJ · mol−1
- ^ ΔfG°, -623.08 kJ · mol−1
- ^ S°, 187.4 J · K−1 · mol−1
- ^ ΔfH°, -950.81 kJ · mol−1
- ^ ΔfG°, -851.0 kJ · mol−1
- ^ S°, 101.7 J · K−1 · mol−1
- ^ Cp°, 87.61 J · K−1 · mol−1
- ^ ΔfH°, -932.11 kJ · mol−1
- ^ ΔfG°, -848.66 kJ · mol−1
- ^ S°, 150.2 J · K−1 · mol−1
- ^ ΔfH°, -943.9 kJ · mol−1
- ^ ΔfG°, -849.7 kJ · mol−1
- ^ S°, 113.8 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1