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Na2SeO3 🔥→ Na2O + SeO2

Decomposition of sodium selenite yields sodium oxide and selenium dioxide (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Thermal decomposition without redox
Thermally decomposable substanceLewis conjugate
🔥
ProductLewis acid + ProductLewis base

Oxidation state of each atom

Decomposition of sodium selenite

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Na2SeO3Sodium selenite1
Lewis conjugate
Thermally decomposable
Oxoacid salt
Salt of oxoacid and hydroxide base

Products

Chemical formulaNameCoefficientTypeType in general
equation
Na2OSodium oxide1
Lewis acid
Lewis base
Basic oxide
SeO2Selenium dioxide1
Lewis acid
Acidic oxide

Thermodynamic changes

Changes in standard condition

Decomposition of sodium selenite
Na2SeO3Crystalline solid
🔥
Na2OCrystalline solid + SeO2Crystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
319.0
per 1 mol of
319.0
per 1 mol of
319.0
per 1 mol of
319.0

Changes in aqueous solution

Decomposition of sodium selenite
Na2SeO3Ionized aqueous solution
🔥
Na2OCrystalline solid + SeO2Aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
353.7
per 1 mol of
353.7
per 1 mol of
353.7
per 1 mol of
353.7

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na2SeO3 (cr)-958.6[1]
Na2SeO3 (ai)-989.5[1]-893.7[1]130[1]
Na2SeO3 (cr)
5 hydrate
-2404.13[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na2O (cr)-414.22[1]-375.46[1]75.06[1]69.12[1]
Na2O (g)-35.6[1]-52.3[1]261.2[1]55.2[1]
SeO2 (cr)-225.35[1]
SeO2 (aq)-221.63[1]
* (cr):Crystalline solid, (g):Gas, (aq):Aqueous solution

References

List of references

  1. 1