Sr(CH3COO)2 + KHCO3 ๐งโ SrCO3โ + CH3COOK + CH3COOH
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The reaction of strontium acetate and potassium hydrogencarbonate yields strontium carbonate, potassium acetate, and acetic acid (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of strontium acetate and potassium hydrogencarbonate
General equation
- Precipitation reaction
- Miscible with water/Very soluble in water/Soluble in waterLewis acid + Miscible with water/Very soluble in water/Soluble in waterLewis base๐งโถ Insoluble in water/Very slightly soluble in water/Slightly soluble in waterLewis conjugate + Product(Non-redox product)
Oxidation state of each atom
- Reaction of strontium acetate and potassium hydrogencarbonate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
Sr(CH3COO)2 | Strontium acetate | 1 | Lewis acid | Very soluble in water |
KHCO3 | Potassium hydrogencarbonate | 1 | Lewis base | Very soluble in water |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
SrCO3 | Strontium carbonate | 1 | Lewis conjugate | Insoluble in water |
CH3COOK | Potassium acetate | 1 | Non-redox product | โ |
CH3COOH | Acetic acid | 1 | Non-redox product | โ |
Thermodynamic changes
Changes in standard condition
- Reaction of strontium acetate and potassium hydrogencarbonate
- Sr(CH3COO)2Crystalline solid + KHCO3Crystalline solidSrCO3โCrystalline solid + CH3COOKCrystalline solid + CH3COOHLiquid๐งโถ
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | 23.0 | โ | โ | โ |
per 1 mol of | 23.0 | โ | โ | โ |
per 1 mol of | 23.0 | โ | โ | โ |
per 1 mol of | 23.0 | โ | โ | โ |
per 1 mol of | 23.0 | โ | โ | โ |
per 1 mol of | 23.0 | โ | โ | โ |
Changes in aqueous solution (1)
- Reaction of strontium acetate and potassium hydrogencarbonate
- Sr(CH3COO)2Aqueous solution + KHCO3Ionized aqueous solutionSrCO3โCrystalline solid + CH3COOKIonized aqueous solution + CH3COOHUn-ionized aqueous solution๐งโถ
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | 12.2 | โ | โ | โ |
per 1 mol of | 12.2 | โ | โ | โ |
per 1 mol of | 12.2 | โ | โ | โ |
per 1 mol of | 12.2 | โ | โ | โ |
per 1 mol of | 12.2 | โ | โ | โ |
per 1 mol of | 12.2 | โ | โ | โ |
Changes in aqueous solution (2)
- Reaction of strontium acetate and potassium hydrogencarbonate
- Sr(CH3COO)2Aqueous solution + KHCO3Ionized aqueous solutionSrCO3โCrystalline solid + CH3COOKIonized aqueous solution + CH3COOHIonized aqueous solution๐งโถ
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | 12.0 | โ | โ | โ |
per 1 mol of | 12.0 | โ | โ | โ |
per 1 mol of | 12.0 | โ | โ | โ |
per 1 mol of | 12.0 | โ | โ | โ |
per 1 mol of | 12.0 | โ | โ | โ |
per 1 mol of | 12.0 | โ | โ | โ |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
---|---|---|---|---|
Sr(CH3COO)2 (cr) | -1487.4[1] | โ | โ | โ |
Sr(CH3COO)2 (aq) | -1512.1[1] | โ | โ | โ |
Sr(CH3COO)2 (cr) 0.5 hydrate | -1631.8[1] | โ | โ | โ |
KHCO3 (cr) | -963.2[1] | -863.5[1] | 115.5[1] | โ |
KHCO3 (ai) | -944.37[1] | -870.04[1] | 193.7[1] | โ |
* (cr):Crystalline solid, (aq):Aqueous solution, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
---|---|---|---|---|
SrCO3 (cr) | -1220.1[1] | -1140.1[1] | 97.1[1] | 81.42[1] |
SrCO3 (ai) | -1222.94[1] | -1087.29[1] | -89.5[1] | โ |
CH3COOK (cr) | -723.0[1] | โ | โ | โ |
CH3COOK (ai) | -738.39[1] | -652.58[1] | 189.1[1] | 15.5[1] |
CH3COOH (l) | -484.5[1] | -389.9[1] | 159.8[1] | 124.3[1] |
CH3COOH (g) | -432.25[1] | -374.0[1] | 282.5[1] | 66.5[1] |
CH3COOH (ai) | -486.01[1] | -369.31[1] | 86.6[1] | -6.3[1] |
CH3COOH (ao) | -485.76[1] | -396.46[1] | 178.7[1] | โ |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid, (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
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- ^ ฮfHยฐ, -1512.1 kJ ยท molโ1
- ^ ฮfHยฐ, -1631.8 kJ ยท molโ1
- ^ ฮfHยฐ, -963.2 kJ ยท molโ1
- ^ ฮfGยฐ, -863.5 kJ ยท molโ1
- ^ Sยฐ, 115.5 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -944.37 kJ ยท molโ1
- ^ ฮfGยฐ, -870.04 kJ ยท molโ1
- ^ Sยฐ, 193.7 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1220.1 kJ ยท molโ1
- ^ ฮfGยฐ, -1140.1 kJ ยท molโ1
- ^ Sยฐ, 97.1 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 81.42 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1222.94 kJ ยท molโ1
- ^ ฮfGยฐ, -1087.29 kJ ยท molโ1
- ^ Sยฐ, -89.5 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -723.0 kJ ยท molโ1
- ^ ฮfHยฐ, -738.39 kJ ยท molโ1
- ^ ฮfGยฐ, -652.58 kJ ยท molโ1
- ^ Sยฐ, 189.1 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 15.5 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -484.5 kJ ยท molโ1
- ^ ฮfGยฐ, -389.9 kJ ยท molโ1
- ^ Sยฐ, 159.8 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 124.3 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -432.25 kJ ยท molโ1
- ^ ฮfGยฐ, -374.0 kJ ยท molโ1
- ^ Sยฐ, 282.5 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 66.5 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -486.01 kJ ยท molโ1
- ^ ฮfGยฐ, -369.31 kJ ยท molโ1
- ^ Sยฐ, 86.6 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, -6.3 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -485.76 kJ ยท molโ1
- ^ ฮfGยฐ, -396.46 kJ ยท molโ1
- ^ Sยฐ, 178.7 J ยท Kโ1 ยท molโ1