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Sr(CH3COO)2 + KHCO3 ๐Ÿ’งโ†’ SrCO3โ†“ + CH3COOK + CH3COOH

The reaction of strontium acetate and potassium hydrogencarbonate yields strontium carbonate, potassium acetate, and acetic acid (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Sr(CH3COO)2Strontium acetate1
Lewis acid
Very soluble in water
KHCO3Potassium hydrogencarbonate1
Lewis base
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
SrCO3Strontium carbonate1
Lewis conjugate
Insoluble in water
CH3COOKPotassium acetate1
Non-redox product
โ€“
CH3COOHAcetic acid1
Non-redox product
โ€“

Thermodynamic changes

Changes in standard condition

Reaction of strontium acetate and potassium hydrogencarbonate
Sr(CH3COO)2Crystalline solid + KHCO3Crystalline solid
๐Ÿ’ง
โŸถ
SrCO3โ†“Crystalline solid + CH3COOKCrystalline solid + CH3COOHLiquid
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
23.0โ€“โ€“โ€“
per 1 mol of
23.0โ€“โ€“โ€“
23.0โ€“โ€“โ€“
23.0โ€“โ€“โ€“
per 1 mol of
23.0โ€“โ€“โ€“
per 1 mol of
23.0โ€“โ€“โ€“

Changes in aqueous solution (1)

Reaction of strontium acetate and potassium hydrogencarbonate
Sr(CH3COO)2Aqueous solution + KHCO3Ionized aqueous solution
๐Ÿ’ง
โŸถ
SrCO3โ†“Crystalline solid + CH3COOKIonized aqueous solution + CH3COOHUn-ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
12.2โ€“โ€“โ€“
per 1 mol of
12.2โ€“โ€“โ€“
12.2โ€“โ€“โ€“
12.2โ€“โ€“โ€“
per 1 mol of
12.2โ€“โ€“โ€“
per 1 mol of
12.2โ€“โ€“โ€“

Changes in aqueous solution (2)

Reaction of strontium acetate and potassium hydrogencarbonate
Sr(CH3COO)2Aqueous solution + KHCO3Ionized aqueous solution
๐Ÿ’ง
โŸถ
SrCO3โ†“Crystalline solid + CH3COOKIonized aqueous solution + CH3COOHIonized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
12.0โ€“โ€“โ€“
per 1 mol of
12.0โ€“โ€“โ€“
12.0โ€“โ€“โ€“
12.0โ€“โ€“โ€“
per 1 mol of
12.0โ€“โ€“โ€“
per 1 mol of
12.0โ€“โ€“โ€“

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Sr(CH3COO)2 (cr)-1487.4[1]โ€“โ€“โ€“
Sr(CH3COO)2 (aq)-1512.1[1]โ€“โ€“โ€“
Sr(CH3COO)2 (cr)
0.5 hydrate
-1631.8[1]โ€“โ€“โ€“
KHCO3 (cr)-963.2[1]-863.5[1]115.5[1]โ€“
KHCO3 (ai)-944.37[1]-870.04[1]193.7[1]โ€“
* (cr):Crystalline solid, (aq):Aqueous solution, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
SrCO3 (cr)-1220.1[1]-1140.1[1]97.1[1]81.42[1]
SrCO3 (ai)-1222.94[1]-1087.29[1]-89.5[1]โ€“
CH3COOK (cr)-723.0[1]โ€“โ€“โ€“
CH3COOK (ai)-738.39[1]-652.58[1]189.1[1]15.5[1]
CH3COOH (l)-484.5[1]-389.9[1]159.8[1]124.3[1]
CH3COOH (g)-432.25[1]-374.0[1]282.5[1]66.5[1]
CH3COOH (ai)-486.01[1]-369.31[1]86.6[1]-6.3[1]
CH3COOH (ao)-485.76[1]-396.46[1]178.7[1]โ€“
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid, (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)