SnOH+ + H2O → Sn(OH)2 + H+
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- Reaction of tin(II) hydroxide ion and water
The reaction of tin(II) hydroxide ion and water yields tin(II) hydroxide and hydrogen ion (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of tin(II) hydroxide ion and water
General equation
- Cation/AnionBrønsted acid + H2OBrønsted base ⟶ Proton accepting ion/BaseConjugate base + H+Conjugate acid
Oxidation state of each atom
- Reaction of tin(II) hydroxide ion and water
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
SnOH+ | Tin(II) hydroxide ion | 1 | Brønsted acid | Cation |
H2O | Water | 1 | Brønsted base | Water |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
Sn(OH)2 | Tin(II) hydroxide | 1 | Conjugate base | Base |
H+ | Hydrogen ion | 1 | Conjugate acid | Hydrogen ion |
Thermodynamic changes
Changes in standard condition
- Reaction of tin(II) hydroxide ion and water◆
ΔrG 0.3 kJ/mol K 0.89 × 100 pK 0.05
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | 10.9 | 0.3 | 35 | – |
per 1 mol of Tin(II) hydroxide ion | 10.9 | 0.30 | 35 | – |
per 1 mol of | 10.9 | 0.30 | 35 | – |
per 1 mol of | 10.9 | 0.30 | 35 | – |
per 1 mol of Hydrogen ion | 10.9 | 0.30 | 35 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
SnOH+ (ao) | -286.2[1] | -254.8[1] | 50[1] | – |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (l):Liquid, (g):Gas
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Sn(OH)2 (cr) precipitated | -561.1[1] | -491.6[1] | 155[1] | – |
H+ (g) | 1536.202[1] | – | – | – |
H+ (ao) | 0[1] | 0[1] | 0[1] | 0[1] |
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -286.2 kJ · mol−1
- ^ ΔfG°, -254.8 kJ · mol−1
- ^ S°, 50. J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1
- ^ ΔfH°, -561.1 kJ · mol−1
- ^ ΔfG°, -491.6 kJ · mol−1
- ^ S°, 155. J · K−1 · mol−1
- ^ ΔfH°, 1536.202 kJ · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 0 J · K−1 · mol−1
- ^ Cp°, 0 J · K−1 · mol−1