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SnSO4 + KHS 💧→ SnS↓ + KHSO4

The reaction of tin(II) sulfate and potassium hydrogensulfide yields tin(II) sulfide and potassium hydrogensulfate. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
SnSO4Tin(II) sulfate1
Lewis acid
Soluble in water
KHSPotassium hydrogensulfide1
Lewis base
Soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
SnSTin(II) sulfide1
Lewis conjugate
Insoluble in water
KHSO4Potassium hydrogensulfate1
Non-redox product

Thermodynamic changes

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
SnSO4
KHS (cr)-265.10[1]75.31[1]
KHS (ai)-269.9[1]-271.19[1]165.3[1]
KHS (cr)
0.25 hydrate
-337.2[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
SnS (cr)-100[1]-98.3[1]77.0[1]49.25[1]
SnS (g)119.2[1]
KHSO4 (cr)-1160.6[1]-1031.3[1]138.1[1]
KHSO4 (ai)-1139.72[1]-1039.18[1]234.3[1]-63[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1