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ZnI2 + 2NaSCN 💧→ Zn(SCN)2↓ + 2NaI

The reaction of zinc iodide and sodium thiocyanate yields zinc thiocyanate and sodium iodide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
ZnI2Zinc iodide1
Lewis acid
Very soluble in water
NaSCNSodium thiocyanate2
Lewis base
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
Zn(SCN)2Zinc thiocyanate1
Lewis conjugate
Slightly soluble in water
NaISodium iodide2
Non-redox product

Thermodynamic changes

Changes in aqueous solution (1)

Reaction of zinc iodide and sodium thiocyanate
ΔrG−5.3 kJ/mol
K8.48 × 100
pK−0.93
ZnI2Ionized aqueous solution + 2NaSCNIonized aqueous solution
💧
Zn(SCN)2Un-ionized aqueous solution + 2NaIIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−5.3
per 1 mol of
−5.3
per 1 mol of
−2.6
per 1 mol of
−5.3
per 1 mol of
−2.6

Changes in aqueous solution (2)

Reaction of zinc iodide and sodium thiocyanate
ΔrG−14.9 kJ/mol
K4.08 × 102
pK−2.61
ZnI2Un-ionized aqueous solution + 2NaSCNIonized aqueous solution
💧
Zn(SCN)2Un-ionized aqueous solution + 2NaIIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−14.9
per 1 mol of
−14.9
per 1 mol of
−7.45
per 1 mol of
−14.9
per 1 mol of
−7.45

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
ZnI2 (cr)-208.03[1]-208.95[1]161.1[1]
ZnI2 (ai)-264.26[1]-250.20[1]110.5[1]-238[1]
ZnI2 (ao)-240.6[1]
NaSCN (cr)-170.50[1]
NaSCN (ai)-163.68[1]-169.18[1]203.3[1]6.3[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Zn(SCN)2 (ao)33.1[1]
NaI (cr)-287.78[1]-286.06[1]98.53[1]52.09[1]
NaI (g)-79.5[1]-121.0[1]248.978[1]36.65[1]
NaI (ai)-295.31[1]-313.47[1]170.3[1]-95.8[1]
NaI (cr)
1 hydrate
-883.096[1]-771.10[1]196.2[1]
* (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1