You-iggy

Zn(MnO4)2 + 2KOH → 2KMnO4 + Zn(OH)2

The reaction of zinc permanganate and potassium hydroxide yields potassium permanganate and zinc hydroxide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Zn(MnO4)2Zinc permanganate1
Brønsted acid
Lewis acid
Salt of weak base
Soluble in water
KOHPotassium hydroxide2
Brønsted base
Lewis base
Strong base
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
KMnO4Potassium permanganate2
Conjugate acid
Non-redox product
Salt of strong base
Zn(OH)2Zinc hydroxide1
Conjugate base
Lewis conjugate
Weak base
Insoluble in water

Thermodynamic changes

Changes in aqueous solution (1)

Reaction of zinc permanganate and potassium hydroxide
Zn(MnO4)2Ionized aqueous solution + 2KOHIonized aqueous solution
2KMnO4Ionized aqueous solution + Zn(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (2)

Reaction of zinc permanganate and potassium hydroxide
Zn(MnO4)2Ionized aqueous solution + 2KOHIonized aqueous solution
2KMnO4Ionized aqueous solution + Zn(OH)2Crystalline solidγ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (3)

Reaction of zinc permanganate and potassium hydroxide
Zn(MnO4)2Ionized aqueous solution + 2KOHIonized aqueous solution
2KMnO4Ionized aqueous solution + Zn(OH)2Crystalline solidβ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Changes in aqueous solution (4)

Reaction of zinc permanganate and potassium hydroxide
Zn(MnO4)2Ionized aqueous solution + 2KOHIonized aqueous solution
2KMnO4Ionized aqueous solution + Zn(OH)2Crystalline solidε
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
457
per 1 mol of
457
229
229
per 1 mol of
457

Changes in aqueous solution (5)

Reaction of zinc permanganate and potassium hydroxide
Zn(MnO4)2Ionized aqueous solution + 2KOHIonized aqueous solution
2KMnO4Ionized aqueous solution + Zn(OH)2Crystalline solidprecipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Zn(MnO4)2 (ai)-251[1]
KOH (cr)-424.764[1]-379.08[1]78.9[1]64.9[1]
KOH (g)-231.0[1]-232.6[1]238.3[1]49.20[1]
KOH (ai)-482.37[1]-440.50[1]91.6[1]-126.8[1]
KOH (cr)
1 hydrate
-748.9[1]-645.1[1]117.2[1]
KOH (cr)
2 hydrate
-1051.0[1]-887.3[1]150.6[1]
* (ai):Ionized aqueous solution, (cr):Crystalline solid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
KMnO4 (cr)-837.2[1]-737.6[1]171.71[1]117.57[1]
KMnO4 (ai)-793.8[1]-730.5[1]293.7[1]-60.2[1]
Zn(OH)2 (cr)
γ
-553.81[1]
Zn(OH)2 (cr)
β
-641.91[1]-553.52[1]81.2[1]
Zn(OH)2 (cr)
ε
-643.25[1]-555.07[1]81.6[1]72.4[1]
Zn(OH)2 (cr)
precipitated
-642.2[1]
Zn(OH)2 (ai)-613.88[1]-461.56[1]-133.5[1]-251[1]
Zn(OH)2 (ao)-522.73[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)