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2(NH4)2CO3 🔥→ 2NH4CN + O2↑ + 4H2O

Decomposition of ammonium carbonate yields ammonium cyanide, oxygen, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Thermal decomposition with redox
Thermally decomposable substanceSelf redox agent
🔥
ProductOxidation product + ProductReduction product
Thermal decomposition of oxoacid salt with redox
Oxoacid saltSelf redox agent
🔥
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Decomposition of ammonium carbonate

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
(NH4)2CO3Ammonium carbonate2
Self redox agent
Thermally decomposable
Oxoacid salt

Products

Chemical formulaNameCoefficientTypeType in general
equation
NH4CNAmmonium cyanide2
Reduced
O2Oxygen1
Oxidized
H2OWater4

Thermodynamic changes

Changes in aqueous solution (1)

Decomposition of ammonium carbonate
ΔrG610.3 kJ/mol
K0.12 × 10−106
pK106.92
2(NH4)2CO3Ionized aqueous solution
🔥
2NH4CNIonized aqueous solution + O2Gas + 4H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
777.0610.3560.0
per 1 mol of
388.5305.1280.0
per 1 mol of
388.5305.1280.0
per 1 mol of
777.0610.3560.0
per 1 mol of
194.3152.6140.0

Changes in aqueous solution (2)

Decomposition of ammonium carbonate
ΔrG626.7 kJ/mol
K0.16 × 10−109
pK109.79
2(NH4)2CO3Ionized aqueous solution
🔥
2NH4CNIonized aqueous solution + O2Un-ionized aqueous solution + 4H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
765.3626.7465.7
per 1 mol of
382.6313.4232.8
per 1 mol of
382.6313.4232.8
per 1 mol of
765.3626.7465.7
per 1 mol of
191.3156.7116.4

Changes in aqueous solution (3)

Decomposition of ammonium carbonate
2(NH4)2CO3Ionized aqueous solution
🔥
2NH4CNAqueous solution + O2Gas + 4H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
805.4
per 1 mol of
402.7
per 1 mol of
402.7
per 1 mol of
805.4
per 1 mol of
201.3

Changes in aqueous solution (4)

Decomposition of ammonium carbonate
2(NH4)2CO3Ionized aqueous solution
🔥
2NH4CNAqueous solution + O2Un-ionized aqueous solution + 4H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
793.7
per 1 mol of
396.9
per 1 mol of
396.9
per 1 mol of
793.7
per 1 mol of
198.4

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
(NH4)2CO3 (ai)-942.15[1]-686.42[1]169.9[1]
* (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NH4CN (cr)0.42[1]134[1]
NH4CN (ai)18.0[1]93.0[1]207.5[1]
NH4CN (aq)32.2[1]
O2 (g)0[1]0[1]205.138[1]29.355[1]
O2 (ao)-11.7[1]16.4[1]110.9[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (aq):Aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution, (l):Liquid

References

List of references

  1. 1