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2CsOH + Li2O 🔥→ Cs2O + 2LiOH

The reaction of caesium hydroxide and lithium oxide yields caesium oxide and lithium hydroxide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
CsOHCaesium hydroxide2
Lewis base
Hydroxide base
Li2OLithium oxide1
Lewis acid
Dehydrating basic oxide

Products

Chemical formulaNameCoefficientTypeType in general
equation
Cs2OCaesium oxide1
Basic oxide
LiOHLithium hydroxide2
Lewis conjugate
Hydroxide base

Thermodynamic changes

Changes in standard condition

Reaction of caesium hydroxide and lithium oxide
2CsOHCrystalline solid + Li2OCrystalline solid
🔥
Cs2OCrystalline solid + 2LiOHCrystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
116.77
per 1 mol of
58.385
per 1 mol of
116.77
per 1 mol of
116.77
per 1 mol of
58.385

Changes in aqueous solution (1)

Reaction of caesium hydroxide and lithium oxide
ΔrG250.38 kJ/mol
K0.14 × 10−43
pK43.86
2CsOHIonized aqueous solution + Li2OCrystalline solid
🔥
Cs2OCrystalline solid + 2LiOHIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
211.75250.38−129.71
per 1 mol of
105.88125.19−64.855
per 1 mol of
211.75250.38−129.71
per 1 mol of
211.75250.38−129.71
per 1 mol of
105.88125.19−64.855

Changes in aqueous solution (2)

Reaction of caesium hydroxide and lithium oxide
ΔrG247.9 kJ/mol
K0.37 × 10−43
pK43.43
2CsOHIonized aqueous solution + Li2OCrystalline solid
🔥
Cs2OCrystalline solid + 2LiOHUn-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
211.9247.9−121.1
per 1 mol of
106.0124.0−60.55
per 1 mol of
211.9247.9−121.1
per 1 mol of
211.9247.9−121.1
per 1 mol of
106.0124.0−60.55

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CsOH (cr)-417.23[1]
CsOH (g)-247[1]-247[1]254.83[1]49.71[1]
CsOH (ai)-488.27[1]-449.25[1]122.30[1]
CsOH (cr)
1 hydrate
-754.04[1]
Li2O (cr)-597.94[1]-561.18[1]37.57[1]54.10[1]
Li2O (g)-160.7[1]-181.6[1]231.48[1]49.83[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Cs2O (cr)-345.77[1]-308.14[1]146.86[1]75.98[1]
LiOH (cr)-484.93[1]-438.95[1]42.80[1]49.66[1]
LiOH (g)-238.1[1]-242.3[1]210.90[1]46.02[1]
LiOH (ai)-508.48[1]-450.58[1]2.80[1]-79.9[1]
LiOH (ao)-508.4[1]-451.8[1]7.1[1]
LiOH (cr)
1 hydrate
-788.01[1]-680.95[1]71.21[1]79.50[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)