2H2 + BaCO3 → Ba(OH)2 + H2O + C
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- Reaction of and barium carbonate
The reaction of and barium carbonate yields barium hydroxide, water, and (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and barium carbonate
General equation
- Reaction of reducing species and reducible species
- Reducing speciesReducing agent + Reducible speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and barium carbonate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| 2 | Reducing | Reducing | ||
| BaCO3 | Barium carbonate | 1 | Oxidizing | Reducible |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Ba(OH)2 | Barium hydroxide | 1 | Oxidized | – |
| H2O | Water | 1 | Oxidized | – |
| 1 | Reduced | – |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of and barium carbonate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −14.2 | – | – | – |
| −7.10 | – | – | – | |
per 1 mol of | −14.2 | – | – | – |
per 1 mol of | −14.2 | – | – | – |
per 1 mol of | −14.2 | – | – | – |
| −14.2 | – | – | – |
Changes in standard condition (2)
- Reaction of and barium carbonate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −12.3 | – | – | – |
| −6.15 | – | – | – | |
per 1 mol of | −12.3 | – | – | – |
per 1 mol of | −12.3 | – | – | – |
per 1 mol of | −12.3 | – | – | – |
| −12.3 | – | – | – |
Changes in aqueous solution
- Reaction of and barium carbonate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −5.8 | – | – | – |
| −2.9 | – | – | – | |
per 1 mol of | −5.8 | – | – | – |
per 1 mol of | −5.8 | – | – | – |
per 1 mol of | −5.8 | – | – | – |
| −5.8 | – | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| (g) | 0[1] | 0[1] | 130.684[1] | 28.824[1] |
| (ao) | -4.2[1] | 17.6[1] | 577[1] | – |
| BaCO3 (cr) | -1216.3[1] | -1137.6[1] | 112.1[1] | 85.35[1] |
| BaCO3 (ai) | -1214.78[1] | -1088.59[1] | -47.3[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Ba(OH)2 (cr) | -944.7[1] | – | – | – |
| Ba(OH)2 (g) | -586[1] | – | – | – |
| Ba(OH)2 (cr) 1 hydrate | -1248.5[1] | – | – | – |
| Ba(OH)2 (cr) 3 hydrate | -1849.3[1] | – | – | – |
| Ba(OH)2 (cr) 8 hydrate | -3342.2[1] | -2792.8[1] | 427[1] | – |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
| (cr) graphite | 0[1] | 0[1] | 5.740[1] | 8.527[1] |
| (cr) diamond | 1.895[1] | 2.900[1] | 2.377[1] | 6.113[1] |
| (g) | 716.682[1] | 671.257[1] | 158.096[1] | 20.838[1] |
* (cr):Crystalline solid, (g):Gas, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 130.684 J · K−1 · mol−1
- ^ Cp°, 28.824 J · K−1 · mol−1
- ^ ΔfH°, -4.2 kJ · mol−1
- ^ ΔfG°, 17.6 kJ · mol−1
- ^ S°, 577 J · K−1 · mol−1
- ^ ΔfH°, -1216.3 kJ · mol−1
- ^ ΔfG°, -1137.6 kJ · mol−1
- ^ S°, 112.1 J · K−1 · mol−1
- ^ Cp°, 85.35 J · K−1 · mol−1
- ^ ΔfH°, -1214.78 kJ · mol−1
- ^ ΔfG°, -1088.59 kJ · mol−1
- ^ S°, -47.3 J · K−1 · mol−1
- ^ ΔfH°, -944.7 kJ · mol−1
- ^ ΔfH°, -586. kJ · mol−1
- ^ ΔfH°, -1248.5 kJ · mol−1
- ^ ΔfH°, -1849.3 kJ · mol−1
- ^ ΔfH°, -3342.2 kJ · mol−1
- ^ ΔfG°, -2792.8 kJ · mol−1
- ^ S°, 427. J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 5.740 J · K−1 · mol−1
- ^ Cp°, 8.527 J · K−1 · mol−1
- ^ ΔfH°, 1.895 kJ · mol−1
- ^ ΔfG°, 2.900 kJ · mol−1
- ^ S°, 2.377 J · K−1 · mol−1
- ^ Cp°, 6.113 J · K−1 · mol−1
- ^ ΔfH°, 716.682 kJ · mol−1
- ^ ΔfG°, 671.257 kJ · mol−1
- ^ S°, 158.096 J · K−1 · mol−1
- ^ Cp°, 20.838 J · K−1 · mol−1