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2H2 + H2CO3 → 3H2O + C

The reaction of hydrogen and carbonic acid yields water and carbon (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and reducible species
Reducing speciesReducing agent + Reducible speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of hydrogen and carbonic acid

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
H2Hydrogen2
Reducing
Reducing
H2CO3Carbonic acid1
Oxidizing
Reducible

Products

Chemical formulaNameCoefficientTypeType in general
equation
H2OWater3
Oxidized
CCarbon1
Reduced

Thermodynamic changes

Changes in standard condition

Reaction of hydrogen and carbonic acid
ΔrG−123.5 kJ/mol
K4.33 × 1021
pK−21.64
2H2Un-ionized aqueous solution + H2CO3Un-ionized aqueous solution
3H2OLiquid + CCrystalline solidgraphite
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−149.4−123.5−1126
per 1 mol of
−74.70−61.75−563.0
per 1 mol of
−149.4−123.5−1126
per 1 mol of
−49.80−41.17−375.3
per 1 mol of
−149.4−123.5−1126

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H2 (g)0[1]0[1]130.684[1]28.824[1]
H2 (ao)-4.2[1]17.6[1]577[1]
H2CO3 (ao)-699.65[1]-623.08[1]187.4[1]
* (g):Gas, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
C (cr)
graphite
0[1]0[1]5.740[1]8.527[1]
C (cr)
diamond
1.895[1]2.900[1]2.377[1]6.113[1]
C (g)716.682[1]671.257[1]158.096[1]20.838[1]
* (cr):Crystalline solid, (l):Liquid, (g):Gas

References

List of references

  1. 1