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2H2 + 2CuSCN → Cu2S + NH4SCN + C

The reaction of hydrogen and copper(I) thiocyanate yields copper(I) sulfide, ammonium thiocyanate, and carbon (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and reducible species
Reducing speciesReducing agent + Reducible speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
H2Hydrogen2
Reducing
Reducing
CuSCNCopper(I) thiocyanate2
Oxidizing
Reducible

Products

Chemical formulaNameCoefficientTypeType in general
equation
Cu2SCopper(I) sulfide1
NH4SCNAmmonium thiocyanate1
Oxidized
CCarbon1
Reduced

Thermodynamic changes

Changes in standard condition (1)

Reaction of hydrogen and copper(I) thiocyanate
2H2Gas + 2CuSCNCrystalline solid
Cu2SCrystalline solidα + NH4SCNCrystalline solid + CCrystalline solidgraphite
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in standard condition (2)

Reaction of hydrogen and copper(I) thiocyanate
2H2Gas + 2CuSCNCrystalline solid
Cu2SCrystalline solidα + NH4SCNCrystalline solid + CCrystalline soliddiamond
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in aqueous solution

Reaction of hydrogen and copper(I) thiocyanate
ΔrG−393.4 kJ/mol
K8.33 × 1068
pK−68.92
2H2Un-ionized aqueous solution + 2CuSCNIonized aqueous solution
Cu2SCrystalline solidα + NH4SCNIonized aqueous solution + CCrystalline solidgraphite
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−423.4−393.4−1139
per 1 mol of
−211.7−196.7−569.5
−211.7−196.7−569.5
per 1 mol of
−423.4−393.4−1139
−423.4−393.4−1139
per 1 mol of
−423.4−393.4−1139

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H2 (g)0[1]0[1]130.684[1]28.824[1]
H2 (ao)-4.2[1]17.6[1]577[1]
CuSCN (cr)69.9[1]
CuSCN (ai)148.11[1]142.69[1]184.9[1]
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Cu2S (cr)
α
-79.5[1]-86.2[1]120.9[1]76.32[1]
NH4SCN (cr)-78.7[1]
NH4SCN (ai)-56.07[1]13.40[1]257.7[1]39.7[1]
C (cr)
graphite
0[1]0[1]5.740[1]8.527[1]
C (cr)
diamond
1.895[1]2.900[1]2.377[1]6.113[1]
C (g)716.682[1]671.257[1]158.096[1]20.838[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas

References

List of references

  1. 1