2H2S + 2Mn(NO3)2 → MnSO4 + 4HNO2 + MnS
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The reaction of hydrogen sulfide and manganese(II) nitrate yields manganese(II) sulfate, nitrous acid, and manganese(II) sulfide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of hydrogen sulfide and manganese(II) nitrate
General equation
- Reaction of reducing species and oxidizing species
- Reducing speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of hydrogen sulfide and manganese(II) nitrate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| H2S | Hydrogen sulfide | 2 | Reducing | Reducing |
| Mn(NO3)2 | Manganese(II) nitrate | 2 | Oxidizing | Oxidizing |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| MnSO4 | Manganese(II) sulfate | 1 | Oxidized | – |
| HNO2 | Nitrous acid | 4 | Reduced | – |
| MnS | Manganese(II) sulfide | 1 | – | – |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of hydrogen sulfide and manganese(II) nitrate◆
ΔrG −449.0 kJ/mol K 4.59 × 1078 pK −78.66
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −456.5 | −449.0 | −21 | – |
per 1 mol of | −228.3 | −224.5 | −11 | – |
per 1 mol of | −228.3 | −224.5 | −11 | – |
per 1 mol of | −456.5 | −449.0 | −21 | – |
per 1 mol of | −114.1 | −112.3 | −5.3 | – |
per 1 mol of | −456.5 | −449.0 | −21 | – |
Changes in standard condition (2)
- Reaction of hydrogen sulfide and manganese(II) nitrate◆
ΔrG −436.0 kJ/mol K 2.42 × 1076 pK −76.38
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −470.7 | −436.0 | −111 | – |
per 1 mol of | −235.3 | −218.0 | −55.5 | – |
per 1 mol of | −235.3 | −218.0 | −55.5 | – |
per 1 mol of | −470.7 | −436.0 | −111 | – |
per 1 mol of | −117.7 | −109.0 | −27.8 | – |
per 1 mol of | −470.7 | −436.0 | −111 | – |
Changes in standard condition (3)
- Reaction of hydrogen sulfide and manganese(II) nitrate◆
ΔrG −449.0 kJ/mol K 4.59 × 1078 pK −78.66
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −456.5 | −449.0 | −21 | – |
per 1 mol of | −228.3 | −224.5 | −11 | – |
per 1 mol of | −228.3 | −224.5 | −11 | – |
per 1 mol of | −456.5 | −449.0 | −21 | – |
per 1 mol of | −114.1 | −112.3 | −5.3 | – |
per 1 mol of | −456.5 | −449.0 | −21 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| H2S (g) | -20.63[1] | -33.56[1] | 205.79[1] | 34.23[1] |
| H2S (ao) | -39.7[1] | -27.83[1] | 121[1] | – |
| Mn(NO3)2 (cr) | -576.26[1] | – | – | – |
| Mn(NO3)2 (ai) | -635.5[1] | -450.9[1] | 218[1] | -121[1] |
| Mn(NO3)2 (vit) 6 hydrate | -2371.9[1] | – | – | – |
| Mn(NO3)2 (l) 6 hydrate | -2331.62[1] | – | – | – |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution, (vit):Vitreous liquid, (l):Liquid
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| MnSO4 (cr) | -1065.25[1] | -957.36[1] | 112.1[1] | 100.50[1] |
| MnSO4 (ai) | -1130.1[1] | -972.7[1] | -53.6[1] | -243[1] |
| MnSO4 (ao) | -1115.9[1] | -985.7[1] | 36.4[1] | – |
| MnSO4 (cr) 1 hydrate α | -1376.5[1] | – | – | – |
| MnSO4 (cr) 1 hydrate β | -1348.1[1] | – | – | – |
| MnSO4 (cr) 4 hydrate | -2258.1[1] | – | – | – |
| MnSO4 (cr) 5 hydrate | -2553.1[1] | – | – | 326[1] |
| MnSO4 (cr) 7 hydrate | -3139.3[1] | – | – | – |
| HNO2 (g) cis | -77.99[1] | -42.94[1] | 248.76[1] | 44.77[1] |
| HNO2 (g) trans | -80.12[1] | -45.24[1] | 249.22[1] | 46.07[1] |
| HNO2 (g) | -79.5[1] | -46.0[1] | 254.1[1] | 45.6[1] |
| HNO2 (ao) | -119.2[1] | -50.6[1] | 135.6[1] | – |
| MnS (cr) green | -214.2[1] | -218.4[1] | 78.2[1] | 49.96[1] |
| MnS (am) precipitated, pink | -213.8[1] | – | – | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (g):Gas, (am):Amorphous solid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -20.63 kJ · mol−1
- ^ ΔfG°, -33.56 kJ · mol−1
- ^ S°, 205.79 J · K−1 · mol−1
- ^ Cp°, 34.23 J · K−1 · mol−1
- ^ ΔfH°, -39.7 kJ · mol−1
- ^ ΔfG°, -27.83 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, -576.26 kJ · mol−1
- ^ ΔfH°, -635.5 kJ · mol−1
- ^ ΔfG°, -450.9 kJ · mol−1
- ^ S°, 218. J · K−1 · mol−1
- ^ Cp°, -121. J · K−1 · mol−1
- ^ ΔfH°, -2371.9 kJ · mol−1
- ^ ΔfH°, -2331.62 kJ · mol−1
- ^ ΔfH°, -1065.25 kJ · mol−1
- ^ ΔfG°, -957.36 kJ · mol−1
- ^ S°, 112.1 J · K−1 · mol−1
- ^ Cp°, 100.50 J · K−1 · mol−1
- ^ ΔfH°, -1130.1 kJ · mol−1
- ^ ΔfG°, -972.7 kJ · mol−1
- ^ S°, -53.6 J · K−1 · mol−1
- ^ Cp°, -243. J · K−1 · mol−1
- ^ ΔfH°, -1115.9 kJ · mol−1
- ^ ΔfG°, -985.7 kJ · mol−1
- ^ S°, 36.4 J · K−1 · mol−1
- ^ ΔfH°, -1376.5 kJ · mol−1
- ^ ΔfH°, -1348.1 kJ · mol−1
- ^ ΔfH°, -2258.1 kJ · mol−1
- ^ ΔfH°, -2553.1 kJ · mol−1
- ^ Cp°, 326. J · K−1 · mol−1
- ^ ΔfH°, -3139.3 kJ · mol−1
- ^ ΔfH°, -77.99 kJ · mol−1
- ^ ΔfG°, -42.94 kJ · mol−1
- ^ S°, 248.76 J · K−1 · mol−1
- ^ Cp°, 44.77 J · K−1 · mol−1
- ^ ΔfH°, -80.12 kJ · mol−1
- ^ ΔfG°, -45.24 kJ · mol−1
- ^ S°, 249.22 J · K−1 · mol−1
- ^ Cp°, 46.07 J · K−1 · mol−1
- ^ ΔfH°, -79.5 kJ · mol−1
- ^ ΔfG°, -46.0 kJ · mol−1
- ^ S°, 254.1 J · K−1 · mol−1
- ^ Cp°, 45.6 J · K−1 · mol−1
- ^ ΔfH°, -119.2 kJ · mol−1
- ^ ΔfG°, -50.6 kJ · mol−1
- ^ S°, 135.6 J · K−1 · mol−1
- ^ ΔfH°, -214.2 kJ · mol−1
- ^ ΔfG°, -218.4 kJ · mol−1
- ^ S°, 78.2 J · K−1 · mol−1
- ^ Cp°, 49.96 J · K−1 · mol−1
- ^ ΔfH°, -213.8 kJ · mol−1