2LiOH + N2O5 → 2LiNO3 + H2O
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The reaction of lithium hydroxide and dinitrogen pentaoxide yields lithium nitrate and water. This reaction is an acid-base reaction and is classified as follows:
- Reaction of base and acidic oxide
- Reaction of hydroxide base and acidic oxide
- Reaction of strong hydroxide base and strongly acidic oxide
Table of contents
Reaction data
Chemical equation
- Reaction of lithium hydroxide and dinitrogen pentaoxide
General equation
- Reaction of base and acidic oxide
- BaseLewis base + Acidic oxideLewis acid + H2O ⟶ Oxoacid saltLewis conjugate + (H2O)
- Reaction of hydroxide base and acidic oxide
- Hydroxide baseLewis base + Acidic oxideLewis acid ⟶ Oxoacid saltLewis conjugate + H2O
- Reaction of strong hydroxide base and strongly acidic oxide
- Strong hydroxide baseLewis base + Strongly acidic oxideLewis acid ⟶ Salt of strong acid and strong baseLewis conjugate + H2O
Oxidation state of each atom
- Reaction of lithium hydroxide and dinitrogen pentaoxide
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| LiOH | Lithium hydroxide | 2 | Lewis base | Base Hydroxide base Strong hydroxide base |
| N2O5 | Dinitrogen pentaoxide | 1 | Lewis acid | Acidic oxide Strongly acidic oxide |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| LiNO3 | Lithium nitrate | 2 | Lewis conjugate | Oxoacid salt Salt of strong acid and strong base |
| H2O | Water | 1 | – | Water |
Thermodynamic changes
Changes in standard condition
- Reaction of lithium hydroxide and dinitrogen pentaoxide◆
ΔrG −235.3 kJ/mol K 1.67 × 1041 pK −41.22
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −239.1 | −235.3 | −13.9 | – |
per 1 mol of | −119.5 | −117.7 | −6.95 | – |
per 1 mol of | −239.1 | −235.3 | −13.9 | – |
per 1 mol of | −119.5 | −117.7 | −6.95 | – |
per 1 mol of | −239.1 | −235.3 | −13.9 | – |
Changes in aqueous solution (1)
- Reaction of lithium hydroxide and dinitrogen pentaoxide◆
ΔrG −258.9 kJ/mol K 2.28 × 1045 pK −45.36
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −197.5 | −258.9 | 206.5 | 56.0 |
per 1 mol of | −98.75 | −129.4 | 103.3 | 28.0 |
per 1 mol of | −197.5 | −258.9 | 206.5 | 56.0 |
per 1 mol of | −98.75 | −129.4 | 103.3 | 28.0 |
per 1 mol of | −197.5 | −258.9 | 206.5 | 56.0 |
Changes in aqueous solution (2)
- Reaction of lithium hydroxide and dinitrogen pentaoxide◆
ΔrG −263.1 kJ/mol K 1.24 × 1046 pK −46.09
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | – | −263.1 | – | – |
per 1 mol of | – | −131.6 | – | – |
per 1 mol of | – | −263.1 | – | – |
per 1 mol of | – | −131.6 | – | – |
per 1 mol of | – | −263.1 | – | – |
Changes in aqueous solution (3)
- Reaction of lithium hydroxide and dinitrogen pentaoxide◆
ΔrG −256.4 kJ/mol K 8.30 × 1044 pK −44.92
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −197.6 | −256.4 | 197.9 | – |
per 1 mol of | −98.80 | −128.2 | 98.95 | – |
per 1 mol of | −197.6 | −256.4 | 197.9 | – |
per 1 mol of | −98.80 | −128.2 | 98.95 | – |
per 1 mol of | −197.6 | −256.4 | 197.9 | – |
Changes in aqueous solution (4)
- Reaction of lithium hydroxide and dinitrogen pentaoxide◆
ΔrG −260.6 kJ/mol K 4.52 × 1045 pK −45.66
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | – | −260.6 | – | – |
per 1 mol of | – | −130.3 | – | – |
per 1 mol of | – | −260.6 | – | – |
per 1 mol of | – | −130.3 | – | – |
per 1 mol of | – | −260.6 | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| LiOH (cr) | -484.93[1] | -438.95[1] | 42.80[1] | 49.66[1] |
| LiOH (g) | -238.1[1] | -242.3[1] | 210.90[1] | 46.02[1] |
| LiOH (ai) | -508.48[1] | -450.58[1] | 2.80[1] | -79.9[1] |
| LiOH (ao) | -508.4[1] | -451.8[1] | 7.1[1] | – |
| LiOH (cr) 1 hydrate | -788.01[1] | -680.95[1] | 71.21[1] | 79.50[1] |
| N2O5 (cr) | -43.1[1] | 113.9[1] | 178.2[1] | 143.1[1] |
| N2O5 (g) | 11.3[1] | 115.1[1] | 355.7[1] | 84.5[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| LiNO3 (cr) | -483.13[1] | -381.1[1] | 90.0[1] | – |
| LiNO3 (ai) | -485.85[1] | -404.5[1] | 160.2[1] | -18.0[1] |
| LiNO3 (ao) | – | -406.6[1] | – | – |
| LiNO3 (cr) 3 hydrate | -1374.4[1] | -1103.5[1] | 223.4[1] | – |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (l):Liquid, (g):Gas
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -484.93 kJ · mol−1
- ^ ΔfG°, -438.95 kJ · mol−1
- ^ S°, 42.80 J · K−1 · mol−1
- ^ Cp°, 49.66 J · K−1 · mol−1
- ^ ΔfH°, -238.1 kJ · mol−1
- ^ ΔfG°, -242.3 kJ · mol−1
- ^ S°, 210.90 J · K−1 · mol−1
- ^ Cp°, 46.02 J · K−1 · mol−1
- ^ ΔfH°, -508.48 kJ · mol−1
- ^ ΔfG°, -450.58 kJ · mol−1
- ^ S°, 2.80 J · K−1 · mol−1
- ^ Cp°, -79.9 J · K−1 · mol−1
- ^ ΔfH°, -508.4 kJ · mol−1
- ^ ΔfG°, -451.8 kJ · mol−1
- ^ S°, 7.1 J · K−1 · mol−1
- ^ ΔfH°, -788.01 kJ · mol−1
- ^ ΔfG°, -680.95 kJ · mol−1
- ^ S°, 71.21 J · K−1 · mol−1
- ^ Cp°, 79.50 J · K−1 · mol−1
- ^ ΔfH°, -43.1 kJ · mol−1
- ^ ΔfG°, 113.9 kJ · mol−1
- ^ S°, 178.2 J · K−1 · mol−1
- ^ Cp°, 143.1 J · K−1 · mol−1
- ^ ΔfH°, 11.3 kJ · mol−1
- ^ ΔfG°, 115.1 kJ · mol−1
- ^ S°, 355.7 J · K−1 · mol−1
- ^ Cp°, 84.5 J · K−1 · mol−1
- ^ ΔfH°, -483.13 kJ · mol−1
- ^ ΔfG°, -381.1 kJ · mol−1
- ^ S°, 90.0 J · K−1 · mol−1
- ^ ΔfH°, -485.85 kJ · mol−1
- ^ ΔfG°, -404.5 kJ · mol−1
- ^ S°, 160.2 J · K−1 · mol−1
- ^ Cp°, -18.0 J · K−1 · mol−1
- ^ ΔfG°, -406.6 kJ · mol−1
- ^ ΔfH°, -1374.4 kJ · mol−1
- ^ ΔfG°, -1103.5 kJ · mol−1
- ^ S°, 223.4 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1