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2PH3 + 21Fe2O3 → Fe3(PO4)2 + 13Fe3O4 + 3H2O

The reaction of phosphine and iron(III) oxide yields iron(II) phosphate, iron(II,III) oxide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and reducible species
Reducing speciesReducing agent + Reducible speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of phosphine and iron(III) oxide

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
PH3Phosphine2
Reducing
Reducing
Fe2O3Iron(III) oxide21
Oxidizing
Reducible

Products

Chemical formulaNameCoefficientTypeType in general
equation
Fe3(PO4)2Iron(II) phosphate1
Redoxed product
Fe3O4Iron(II,III) oxide13
Reduced
H2OWater3

Thermodynamic changes

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
PH3 (g)5.4[1]13.4[1]210.23[1]37.11[1]
PH3 (ao)-9.50[1]25.36[1]120.1[1]
Fe2O3 (cr)-824.2[1]-742.2[1]87.40[1]103.85[1]
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Fe3(PO4)2
Fe3O4 (cr)-1118.4[1]-1015.4[1]146.4[1]143.43[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (l):Liquid, (g):Gas

References

List of references

  1. 1