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2KI + 2CsClO4 + 2H+ → 2K+ + CsIO3 + 2ClO2↑ + CsI + H2O

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Reaction of potassium iodide and caesium perchlorate under acidic condition
2KIPotassium iodide + 2CsClO4Caesium perchlorate + 2H+Hydrogen ion
⟶
2K+Potassium ion + CsIO3Caesium iodate + 2ClO2↑Chlorine dioxide + CsICaesium iodide + H2OWater

The reaction of potassium iodide, caesium perchlorate, and hydrogen ion yields potassium ion, caesium iodate, chlorine dioxide, caesium iodide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of potassium iodide and caesium perchlorate under acidic condition
2KIPotassium iodide + 2CsClO4Caesium perchlorate + 2H+Hydrogen ion
⟶
2K+Potassium ion + CsIO3Caesium iodate + 2ClO2↑Chlorine dioxide + CsICaesium iodide + H2OWater

General equation

Reaction of oxidizable species and oxidizing species under acidic condition
Oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent + H+Non-redox agent
⟶
ProductOxidation product + ProductReduction product + H2ONon-redox product

Oxidation state of each atom

Reaction of potassium iodide and caesium perchlorate under acidic condition

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
KIPotassium iodide2
Reducing
Oxidizable
CsClO4Caesium perchlorate2
Oxidizing
Oxidizing under acidic condition
H+Hydrogen ion2
–
Hydrogen ion

Products

Chemical formulaNameCoefficientTypeType in general
equation
K+Potassium ion2
–
–
CsIO3Caesium iodate1
Oxidized
–
ClO2Chlorine dioxide2
Reduced
–
CsICaesium iodide1
–
–
H2OWater1
–
Water

Thermodynamic changes

Changes in standard condition (1)

Reaction of potassium iodide and caesium perchlorate under acidic condition
◆
ΔrG−55.5 kJ/mol
K5.29 × 109
pK−9.72
2KIIonized aqueous solution + 2CsClO4Ionized aqueous solution + 2H+Un-ionized aqueous solution
⟶
2K+Un-ionized aqueous solution + CsIO3Ionized aqueous solution + 2ClO2↑Gas + CsIIonized aqueous solution + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
11.8−55.5226.6–
per 1 mol of
5.90−27.8113.3–
5.90−27.8113.3–
per 1 mol of
Hydrogen ion
5.90−27.8113.3–
per 1 mol of
Potassium ion
5.90−27.8113.3–
per 1 mol of
11.8−55.5226.6–
per 1 mol of
5.90−27.8113.3–
per 1 mol of
11.8−55.5226.6–
per 1 mol of
11.8−55.5226.6–

Changes in standard condition (2)

Reaction of potassium iodide and caesium perchlorate under acidic condition
◆
ΔrG−56.3 kJ/mol
K7.30 × 109
pK−9.86
2KIIonized aqueous solution + 2CsClO4Ionized aqueous solution + 2H+Un-ionized aqueous solution
⟶
2K+Un-ionized aqueous solution + CsIO3Ionized aqueous solution + 2ClO2↑Un-ionized aqueous solution + CsIIonized aqueous solution + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−43.4−56.342.5–
per 1 mol of
−21.7−28.121.3–
−21.7−28.121.3–
per 1 mol of
Hydrogen ion
−21.7−28.121.3–
per 1 mol of
Potassium ion
−21.7−28.121.3–
per 1 mol of
−43.4−56.342.5–
per 1 mol of
−21.7−28.121.3–
per 1 mol of
−43.4−56.342.5–
per 1 mol of
−43.4−56.342.5–

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
KI (cr)-327.900[1]-324.892[1]106.32[1]52.93[1]
KI (g)-125.5[1]-166.1[1]258.3[1]37.11[1]
KI (ai)-307.57[1]-334.85[1]213.8[1]-120.5[1]
CsClO4 (cr)-443.09[1]-314.26[1]175.06[1]108.28[1]
CsClO4 (ai)-387.61[1]-300.54[1]315.1[1]–
H+ (g)1536.202[1]–––
H+ (ao)0[1]0[1]0[1]0[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
K+ (g)514.26[1]–––
K+ (ao)-252.38[1]-283.27[1]102.5[1]21.8[1]
CsIO3 (cr)–-433.8[1]––
CsIO3 (ai)-479.5[1]-420.0[1]251.5[1]–
ClO2 (g)102.5[1]120.5[1]256.84[1]41.97[1]
ClO2 (ao)74.9[1]120.1[1]164.8[1]–
CsI (cr)-346.60[1]-340.58[1]123.05[1]52.80[1]
CsI (g)-151.9[1]-191.2[1]275.29[1]37.45[1]
CsI (ai)-313.47[1]-343.59[1]244.3[1]-152.7[1]
H2O (cr)––––
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)