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2Rb2SO4 🔥→ 2Rb2O + 2S + 3O2

Decomposition of rubidium sulfate yields rubidium oxide, sulfur, and oxygen (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Thermal decomposition with redox
Thermally decomposable substanceSelf redox agent
🔥
ProductOxidation product + ProductReduction product
Thermal decomposition of oxoacid salt with redox
Oxoacid saltSelf redox agent
🔥
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Decomposition of rubidium sulfate

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Rb2SO4Rubidium sulfate2
Self redox agent
Thermally decomposable
Oxoacid salt

Products

Chemical formulaNameCoefficientTypeType in general
equation
Rb2ORubidium oxide2
SSulfur2
Reduced
O2Oxygen3
Oxidized

Thermodynamic changes

Changes in standard condition (1)

Decomposition of rubidium sulfate
2Rb2SO4Crystalline solid
🔥
2Rb2OCrystalline solid + 2SCrystalline solidrhombic + 3O2Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
2193
per 1 mol of
1097
per 1 mol of
1097
per 1 mol of
1097
per 1 mol of
731.0

Changes in standard condition (2)

Decomposition of rubidium sulfate
2Rb2SO4Crystalline solid
🔥
2Rb2OCrystalline solid + 2SCrystalline solidmonoclinic + 3O2Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
2194
per 1 mol of
1097
per 1 mol of
1097
per 1 mol of
1097
per 1 mol of
731.3

Changes in aqueous solution (1)

Decomposition of rubidium sulfate
2Rb2SO4Ionized aqueous solution
🔥
2Rb2OCrystalline solid + 2SCrystalline solidrhombic + 3O2Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
2145
per 1 mol of
1073
per 1 mol of
1073
per 1 mol of
1073
per 1 mol of
715.0

Changes in aqueous solution (2)

Decomposition of rubidium sulfate
2Rb2SO4Ionized aqueous solution
🔥
2Rb2OCrystalline solid + 2SCrystalline solidrhombic + 3O2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
2110
per 1 mol of
1055
per 1 mol of
1055
per 1 mol of
1055
per 1 mol of
703.3

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Rb2SO4 (cr)-1435.61[1]-1316.89[1]197.44[1]134.06[1]
Rb2SO4 (g)-1068.6[1]
Rb2SO4 (ai)-1411.60[1]-1312.50[1]263.2[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Rb2O (cr)-339[1]
Rb2O (g)-50[1]
S (cr)
rhombic
0[1]0[1]31.80[1]22.64[1]
S (cr)
monoclinic
0.33[1]
S (g)278.805[1]238.250[1]167.821[1]23.673[1]
O2 (g)0[1]0[1]205.138[1]29.355[1]
O2 (ao)-11.7[1]16.4[1]110.9[1]
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1