2AgOH + SrO → Ag2O + Sr(OH)2
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- Reaction of silver(I) hydroxide and strontium oxide
The reaction of silver(I) hydroxide and strontium oxide yields silver(I) oxide and strontium hydroxide. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of silver(I) hydroxide and strontium oxide
General equation
- Hydroxide baseLewis base + Dehydrating basic oxideLewis acid ⟶ Basic oxide + Hydroxide baseLewis conjugate
Oxidation state of each atom
- Reaction of silver(I) hydroxide and strontium oxide
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| AgOH | Silver(I) hydroxide | 2 | Lewis base | Hydroxide base |
| SrO | Strontium oxide | 1 | Lewis acid | Dehydrating basic oxide |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Ag2O | Silver(I) oxide | 1 | – | Basic oxide |
| Sr(OH)2 | Strontium hydroxide | 1 | Lewis conjugate | Hydroxide base |
Thermodynamic changes
Changes in aqueous solution (1)
- Reaction of silver(I) hydroxide and strontium oxide
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −149.2 | – | – | – |
per 1 mol of Silver(I) hydroxide | −74.60 | – | – | – |
per 1 mol of | −149.2 | – | – | – |
per 1 mol of | −149.2 | – | – | – |
per 1 mol of | −149.2 | – | – | – |
Changes in aqueous solution (2)
- Reaction of silver(I) hydroxide and strontium oxide
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
per 1 mol of Silver(I) hydroxide | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| AgOH (ai) | -124.415[1] | -80.137[1] | 61.92[1] | -126.8[1] |
| AgOH (ao) | – | -92.0[1] | – | – |
| SrO (cr) | -592.0[1] | -561.9[1] | 54.4[1] | 45.02[1] |
| SrO (g) | -8[1] | – | – | – |
* (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (g):Gas
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Ag2O (cr) | -31.05[1] | -11.20[1] | 121.3[1] | 65.86[1] |
| Sr(OH)2 (cr) | -959.0[1] | – | – | – |
| Sr(OH)2 (g) | -565[1] | – | – | – |
| Sr(OH)2 (cr) 1 hydrate | -1264.8[1] | – | – | – |
| Sr(OH)2 (cr) 8 hydrate | -3352.2[1] | – | – | – |
* (cr):Crystalline solid, (g):Gas
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -124.415 kJ · mol−1
- ^ ΔfG°, -80.137 kJ · mol−1
- ^ S°, 61.92 J · K−1 · mol−1
- ^ Cp°, -126.8 J · K−1 · mol−1
- ^ ΔfG°, -92.0 kJ · mol−1
- ^ ΔfH°, -592.0 kJ · mol−1
- ^ ΔfG°, -561.9 kJ · mol−1
- ^ S°, 54.4 J · K−1 · mol−1
- ^ Cp°, 45.02 J · K−1 · mol−1
- ^ ΔfH°, -8. kJ · mol−1
- ^ ΔfH°, -31.05 kJ · mol−1
- ^ ΔfG°, -11.20 kJ · mol−1
- ^ S°, 121.3 J · K−1 · mol−1
- ^ Cp°, 65.86 J · K−1 · mol−1
- ^ ΔfH°, -959.0 kJ · mol−1
- ^ ΔfH°, -565. kJ · mol−1
- ^ ΔfH°, -1264.8 kJ · mol−1
- ^ ΔfH°, -3352.2 kJ · mol−1