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2NaOH + Li2O 🔥→ Na2O + 2LiOH

The reaction of sodium hydroxide and lithium oxide yields sodium oxide and lithium hydroxide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NaOHSodium hydroxide2
Lewis base
Hydroxide base
Li2OLithium oxide1
Lewis acid
Dehydrating basic oxide

Products

Chemical formulaNameCoefficientTypeType in general
equation
Na2OSodium oxide1
Basic oxide
LiOHLithium hydroxide2
Lewis conjugate
Hydroxide base

Thermodynamic changes

Changes in standard condition

Reaction of sodium hydroxide and lithium oxide
ΔrG66.81 kJ/mol
K0.20 × 10−11
pK11.70
2NaOHCrystalline solid + Li2OCrystalline solid
🔥
Na2OCrystalline solid + 2LiOHCrystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
65.0866.81−5.82−4.74
per 1 mol of
32.5433.41−2.91−2.37
per 1 mol of
65.0866.81−5.82−4.74
per 1 mol of
65.0866.81−5.82−4.74
per 1 mol of
32.5433.41−2.91−2.37

Changes in aqueous solution (1)

Reaction of sodium hydroxide and lithium oxide
ΔrG122.86 kJ/mol
K0.30 × 10−21
pK21.52
2NaOHIonized aqueous solution + Li2OCrystalline solid
🔥
Na2OCrystalline solid + 2LiOHIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
106.99122.86−53.159.4
per 1 mol of
53.49561.430−26.629.7
per 1 mol of
106.99122.86−53.159.4
per 1 mol of
106.99122.86−53.159.4
per 1 mol of
53.49561.430−26.629.7

Changes in aqueous solution (2)

Reaction of sodium hydroxide and lithium oxide
ΔrG120.4 kJ/mol
K0.81 × 10−21
pK21.09
2NaOHIonized aqueous solution + Li2OCrystalline solid
🔥
Na2OCrystalline solid + 2LiOHUn-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
107.1120.4−44.5
per 1 mol of
53.5560.20−22.3
per 1 mol of
107.1120.4−44.5
per 1 mol of
107.1120.4−44.5
per 1 mol of
53.5560.20−22.3

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NaOH (cr)-425.609[1]-379.494[1]64.455[1]59.54[1]
NaOH (g)-207.1[1]-210.0[1]228.43[1]48.37[1]
NaOH (ai)-470.114[1]-419.150[1]48.1[1]-102.1[1]
NaOH (cr)
1 hydrate
-734.543[1]-629.338[1]99.50[1]90.17[1]
NaOH (l)
2 hydrate
-1019.076[1]-873.091[1]195.979[1]239.41[1]
NaOH (l)
3.5 hydrate
-1459.798[1]-1236.356[1]286.089[1]354.43[1]
NaOH (l)
4 hydrate
-1605.15[1]-1356.64[1]318.70[1]
NaOH (l)
5 hydrate
-1894.31[1]-1596.34[1]386.06[1]
NaOH (l)
7 hydrate
-2469.02[1]-2073.80[1]526.31[1]
Li2O (cr)-597.94[1]-561.18[1]37.57[1]54.10[1]
Li2O (g)-160.7[1]-181.6[1]231.48[1]49.83[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (l):Liquid

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na2O (cr)-414.22[1]-375.46[1]75.06[1]69.12[1]
Na2O (g)-35.6[1]-52.3[1]261.2[1]55.2[1]
LiOH (cr)-484.93[1]-438.95[1]42.80[1]49.66[1]
LiOH (g)-238.1[1]-242.3[1]210.90[1]46.02[1]
LiOH (ai)-508.48[1]-450.58[1]2.80[1]-79.9[1]
LiOH (ao)-508.4[1]-451.8[1]7.1[1]
LiOH (cr)
1 hydrate
-788.01[1]-680.95[1]71.21[1]79.50[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)