2Na + Mn3O4 → Na2O + 3MnO
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- Reaction of and manganese(II,III) oxide
The reaction of and manganese(II,III) oxide yields sodium oxide and manganese(II) oxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and manganese(II,III) oxide
General equation
- Reaction of reducing species and oxidizing species
- Reducing speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and manganese(II,III) oxide
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| 2 | Reducing | Reducing | ||
| Mn3O4 | Manganese(II,III) oxide | 1 | Oxidizing | Oxidizing |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Na2O | Sodium oxide | 1 | Oxidized | – |
| MnO | Manganese(II) oxide | 3 | Reduced | – |
Thermodynamic changes
Changes in standard condition
- Reaction of and manganese(II,III) oxide◆
ΔrG −181.0 kJ/mol K 5.13 × 1031 pK −31.71
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −182.1 | −181.0 | −3.8 | 9.30 |
| −91.05 | −90.50 | −1.9 | 4.65 | |
per 1 mol of | −182.1 | −181.0 | −3.8 | 9.30 |
per 1 mol of | −182.1 | −181.0 | −3.8 | 9.30 |
per 1 mol of | −60.70 | −60.33 | −1.3 | 3.10 |
Changes in aqueous solution
- Reaction of and manganese(II,III) oxide◆
ΔrG −181.0 kJ/mol K 5.13 × 1031 pK −31.71
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −182.1 | −181.0 | −3.8 | 9.30 |
| −91.05 | −90.50 | −1.9 | 4.65 | |
per 1 mol of | −182.1 | −181.0 | −3.8 | 9.30 |
per 1 mol of | −182.1 | −181.0 | −3.8 | 9.30 |
per 1 mol of | −60.70 | −60.33 | −1.3 | 3.10 |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| (cr) | 0[1] | 0[1] | 51.21[1] | 28.24[1] |
| (g) | 107.32[1] | 76.761[1] | 153.712[1] | 20.786[1] |
| Mn3O4 (cr) | -1387.8[1] | -1283.2[1] | 155.6[1] | 139.66[1] |
* (cr):Crystalline solid, (g):Gas
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Na2O (cr) | -414.22[1] | -375.46[1] | 75.06[1] | 69.12[1] |
| Na2O (g) | -35.6[1] | -52.3[1] | 261.2[1] | 55.2[1] |
| MnO (cr) | -385.22[1] | -362.90[1] | 59.71[1] | 45.44[1] |
| MnO (g) | 124.22[1] | – | – | – |
* (cr):Crystalline solid, (g):Gas
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 51.21 J · K−1 · mol−1
- ^ Cp°, 28.24 J · K−1 · mol−1
- ^ ΔfH°, 107.32 kJ · mol−1
- ^ ΔfG°, 76.761 kJ · mol−1
- ^ S°, 153.712 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -1387.8 kJ · mol−1
- ^ ΔfG°, -1283.2 kJ · mol−1
- ^ S°, 155.6 J · K−1 · mol−1
- ^ Cp°, 139.66 J · K−1 · mol−1
- ^ ΔfH°, -414.22 kJ · mol−1
- ^ ΔfG°, -375.46 kJ · mol−1
- ^ S°, 75.06 J · K−1 · mol−1
- ^ Cp°, 69.12 J · K−1 · mol−1
- ^ ΔfH°, -35.6 kJ · mol−1
- ^ ΔfG°, -52.3 kJ · mol−1
- ^ S°, 261.2 J · K−1 · mol−1
- ^ Cp°, 55.2 J · K−1 · mol−1
- ^ ΔfH°, -385.22 kJ · mol−1
- ^ ΔfG°, -362.90 kJ · mol−1
- ^ S°, 59.71 J · K−1 · mol−1
- ^ Cp°, 45.44 J · K−1 · mol−1
- ^ ΔfH°, 124.22 kJ · mol−1