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3Cu + NiCO3 🔥→ 3CuO + Ni + C

The reaction of copper and nickel(II) carbonate yields copper(II) oxide, nickel, and carbon (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of oxidizable species and reducible species
Oxidizable speciesReducing agent + Reducible speciesOxidizing agent
🔥
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
CuCopper3
Reducing
Oxidizable
NiCO3Nickel(II) carbonate1
Oxidizing
Reducible

Products

Chemical formulaNameCoefficientTypeType in general
equation
CuOCopper(II) oxide3
Oxidized
NiNickel1
Reduced
CCarbon1
Reduced

Thermodynamic changes

Changes in standard condition (1)

Reaction of copper and nickel(II) carbonate
ΔrG223.4 kJ/mol
K0.73 × 10−39
pK39.14
3CuCrystalline solid + NiCO3Crystalline solid
🔥
3CuOCrystalline solid + NiCrystalline solid + CCrystalline solidgraphite
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
223.4
per 1 mol of
74.47
223.4
per 1 mol of
74.47
per 1 mol of
223.4
per 1 mol of
223.4

Changes in standard condition (2)

Reaction of copper and nickel(II) carbonate
ΔrG226.3 kJ/mol
K0.23 × 10−39
pK39.65
3CuCrystalline solid + NiCO3Crystalline solid
🔥
3CuOCrystalline solid + NiCrystalline solid + CCrystalline soliddiamond
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
226.3
per 1 mol of
75.43
226.3
per 1 mol of
75.43
per 1 mol of
226.3
per 1 mol of
226.3

Changes in aqueous solution

Reaction of copper and nickel(II) carbonate
ΔrG223.4 kJ/mol
K0.73 × 10−39
pK39.14
3CuCrystalline solid + NiCO3Crystalline solid
🔥
3CuOCrystalline solid + NiCrystalline solid + CCrystalline solidgraphite
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
223.4
per 1 mol of
74.47
223.4
per 1 mol of
74.47
per 1 mol of
223.4
per 1 mol of
223.4

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Cu (cr)0[1]0[1]33.150[1]24.435[1]
Cu (g)338.32[1]298.58[1]166.38[1]20.786[1]
NiCO3 (cr)-612.5[1]
* (cr):Crystalline solid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CuO (cr)-157.3[1]-129.7[1]42.63[1]42.30[1]
Ni (cr)0[1]0[1]29.87[1]26.07[1]
Ni (g)429.7[1]384.5[1]182.193[1]23.359[1]
C (cr)
graphite
0[1]0[1]5.740[1]8.527[1]
C (cr)
diamond
1.895[1]2.900[1]2.377[1]6.113[1]
C (g)716.682[1]671.257[1]158.096[1]20.838[1]
* (cr):Crystalline solid, (g):Gas

References

List of references

  1. 1