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3PtCl4 + 12KMnO4 + 18H2O → 3Pt(OH)4 + 10KClO3 + 12Mn(OH)2 + 2KCl

The reaction of platinum(IV) chloride, potassium permanganate, and water yields platinum(IV) hydroxide, potassium chlorate, manganese(II) hydroxide, and potassium chloride (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of hardly oxidizable species and oxidizing species under neutral condition
Hardly oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent + H2ONon-redox agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of platinum(IV) chloride and potassium permanganate under neutral condition

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
PtCl4Platinum(IV) chloride3
Reducing
Hardly oxidizable
KMnO4Potassium permanganate12
Oxidizing
Oxidizing
H2OWater18
Water

Products

Chemical formulaNameCoefficientTypeType in general
equation
Pt(OH)4Platinum(IV) hydroxide3
KClO3Potassium chlorate10
Oxidized
Mn(OH)2Manganese(II) hydroxide12
Reduced
KClPotassium chloride2

Thermodynamic changes

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
PtCl4 (cr)-231.8[1]
PtCl4 (aq)-314.2[1]
PtCl4 (cr)
5 hydrate
-1752.7[1]
KMnO4 (cr)-837.2[1]-737.6[1]171.71[1]117.57[1]
KMnO4 (ai)-793.8[1]-730.5[1]293.7[1]-60.2[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (aq):Aqueous solution, (ai):Ionized aqueous solution, (l):Liquid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Pt(OH)4
KClO3 (cr)-397.73[1]-296.25[1]143.1[1]100.25[1]
KClO3 (ai)-356.35[1]-291.22[1]264.8[1]
Mn(OH)2 (am)
precipitated
-695.4[1]-615.0[1]99.2[1]
KCl (cr)-436.747[1]-409.14[1]82.59[1]51.30[1]
KCl (g)-214.14[1]-233.0[1]239.10[1]36.48[1]
KCl (ai)-419.53[1]-414.49[1]159.0[1]-114.6[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (am):Amorphous solid, (g):Gas

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)