3K+ + PO43− → K3PO4
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- Reaction of potassium ion and phosphate ion
The reaction of potassium ion and phosphate ion yields potassium phosphate (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of potassium ion and phosphate ion
General equation
- Reaction of cation and anion
- CationLewis acid + AnionLewis base ⟶ ProductLewis conjugate + (H2O)
Oxidation state of each atom
- Reaction of potassium ion and phosphate ion
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| K+ | Potassium ion | 3 | Lewis acid | Cation |
| PO43− | Phosphate ion | 1 | Lewis base | Anion |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| K3PO4 | Potassium phosphate | 1 | Lewis conjugate | – |
Thermodynamic changes
Changes in standard condition
- Reaction of potassium ion and phosphate ion◆
ΔrG −0.2 kJ/mol K 1.08 × 100 pK −0.04
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −0.2 | −0.2 | 0.0 | – |
per 1 mol of Potassium ion | −0.067 | −0.067 | 0.0 | – |
per 1 mol of Phosphate ion | −0.20 | −0.20 | 0.0 | – |
per 1 mol of | −0.20 | −0.20 | 0.0 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| K+ (g) | 514.26[1] | – | – | – |
| K+ (ao) | -252.38[1] | -283.27[1] | 102.5[1] | 21.8[1] |
| PO43− (ao) | -1277.4[1] | -1018.7[1] | -220.3[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| K3PO4 (cr) | -1950.2[1] | – | – | – |
| K3PO4 (ai) | -2034.7[1] | -1868.7[1] | 87.2[1] | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 514.26 kJ · mol−1
- ^ ΔfH°, -252.38 kJ · mol−1
- ^ ΔfG°, -283.27 kJ · mol−1
- ^ S°, 102.5 J · K−1 · mol−1
- ^ Cp°, 21.8 J · K−1 · mol−1
- ^ ΔfH°, -1277.4 kJ · mol−1
- ^ ΔfG°, -1018.7 kJ · mol−1
- ^ S°, -220.3 J · K−1 · mol−1
- ^ ΔfH°, -1950.2 kJ · mol−1
- ^ ΔfH°, -2034.7 kJ · mol−1
- ^ ΔfG°, -1868.7 kJ · mol−1
- ^ S°, 87.2 J · K−1 · mol−1