You-iggy

4CsClO3 🔥→ 3CsClO4 + CsCl

Decomposition of caesium chlorate yields caesium perchlorate and caesium chloride (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Thermal decomposition with redox
Thermally decomposable substanceSelf redox agent
🔥
ProductOxidation product + ProductReduction product
Thermal decomposition of oxoacid salt with redox
Oxoacid saltSelf redox agent
🔥
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Decomposition of caesium chlorate

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
CsClO3Caesium chlorate4
Thermally decomposable
Oxoacid salt

Products

Chemical formulaNameCoefficientTypeType in general
equation
CsClO4Caesium perchlorate3
Oxidized
CsClCaesium chloride1
Reduced

Thermodynamic changes

Changes in standard condition

Decomposition of caesium chlorate
ΔrG−125.7 kJ/mol
K1.05 × 1022
pK−22.02
4CsClO3Crystalline solid
🔥
3CsClO4Crystalline solid + CsClCrystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−125.5−125.71.9
per 1 mol of
−31.38−31.430.47
−41.83−41.900.63
per 1 mol of
−125.5−125.71.9

Changes in aqueous solution

Decomposition of caesium chlorate
ΔrG−124.98 kJ/mol
K7.86 × 1021
pK−21.90
4CsClO3Ionized aqueous solution
🔥
3CsClO4Ionized aqueous solution + CsClIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−139.26−124.98−46.8
per 1 mol of
−34.815−31.245−11.7
−46.420−41.660−15.6
per 1 mol of
−139.26−124.98−46.8

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CsClO3 (cr)-411.7[1]-307.9[1]156.1[1]
CsClO3 (ai)-362.25[1]-299.97[1]295.4[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CsClO4 (cr)-443.09[1]-314.26[1]175.06[1]108.28[1]
CsClO4 (ai)-387.61[1]-300.54[1]315.1[1]
CsCl (cr)-443.04[1]-414.53[1]101.17[1]52.47[1]
CsCl (g)-240.20[1]-257.80[1]255.96[1]36.94[1]
CsCl (ai)-425.43[1]-423.24[1]189.54[1]-146.9[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas

References

List of references

  1. 1