4Cu + RbNO3 + 10H+ → 4Cu2+ + NH4+ + Rb+ + 3H2O
Last updated:
- Reaction of and rubidium nitrate under acidic condition
- 4 + RbNO3Rubidium nitrate + 10H+Hydrogen ion4Cu2+Copper(II) ion + NH4+Ammonium ion + Rb+Rubidium ion + 3H2OWater⟶
The reaction of , rubidium nitrate, and hydrogen ion yields copper(II) ion, ammonium ion, rubidium ion, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and rubidium nitrate under acidic condition
- 4 + RbNO3Rubidium nitrate + 10H+Hydrogen ion4Cu2+Copper(II) ion + NH4+Ammonium ion + Rb+Rubidium ion + 3H2OWater⟶
General equation
- Reaction of oxidizable species and oxidizing species under acidic condition
- Oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent + H+Non-redox agent ⟶ ProductOxidation product + ProductReduction product + H2ONon-redox product
Oxidation state of each atom
- Reaction of and rubidium nitrate under acidic condition
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
4 | Reducing | Oxidizable | ||
RbNO3 | Rubidium nitrate | 1 | Oxidizing | Oxidizing under acidic condition |
H+ | Hydrogen ion | 10 | – | Hydrogen ion |
Products
Thermodynamic changes
Changes in standard condition
- Reaction of and rubidium nitrate under acidic condition◆
ΔrG −417.48 kJ/mol K 1.38 × 1073 pK −73.14
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −523.57 | −417.48 | −354.2 | – |
−130.89 | −104.37 | −88.55 | – | |
per 1 mol of | −523.57 | −417.48 | −354.2 | – |
per 1 mol of Hydrogen ion | −52.357 | −41.748 | −35.42 | – |
per 1 mol of Copper(II) ion | −130.89 | −104.37 | −88.55 | – |
per 1 mol of Ammonium ion | −523.57 | −417.48 | −354.2 | – |
per 1 mol of Rubidium ion | −523.57 | −417.48 | −354.2 | – |
per 1 mol of | −174.52 | −139.16 | −118.1 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(cr) | 0[1] | 0[1] | 33.150[1] | 24.435[1] |
(g) | 338.32[1] | 298.58[1] | 166.38[1] | 20.786[1] |
RbNO3 (cr) | -495.05[1] | -395.78[1] | 147.3[1] | 102.1[1] |
RbNO3 (ai) | -458.52[1] | -395.24[1] | 267.8[1] | – |
H+ (g) | 1536.202[1] | – | – | – |
H+ (ao) | 0[1] | 0[1] | 0[1] | 0[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Cu2+ (g) | 3054.07[1] | – | – | – |
Cu2+ (ao) | 64.77[1] | 65.49[1] | -99.6[1] | – |
NH4+ (ao) | -132.51[1] | -79.31[1] | 113.4[1] | 79.9[1] |
Rb+ (g) | 490.101[1] | – | – | – |
Rb+ (ao) | -251.17[1] | -283.98[1] | 121.50[1] | – |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 33.150 J · K−1 · mol−1
- ^ Cp°, 24.435 J · K−1 · mol−1
- ^ ΔfH°, 338.32 kJ · mol−1
- ^ ΔfG°, 298.58 kJ · mol−1
- ^ S°, 166.38 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -495.05 kJ · mol−1
- ^ ΔfG°, -395.78 kJ · mol−1
- ^ S°, 147.3 J · K−1 · mol−1
- ^ Cp°, 102.1 J · K−1 · mol−1
- ^ ΔfH°, -458.52 kJ · mol−1
- ^ ΔfG°, -395.24 kJ · mol−1
- ^ S°, 267.8 J · K−1 · mol−1
- ^ ΔfH°, 1536.202 kJ · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 0 J · K−1 · mol−1
- ^ Cp°, 0 J · K−1 · mol−1
- ^ ΔfH°, 3054.07 kJ · mol−1
- ^ ΔfH°, 64.77 kJ · mol−1
- ^ ΔfG°, 65.49 kJ · mol−1
- ^ S°, -99.6 J · K−1 · mol−1
- ^ ΔfH°, -132.51 kJ · mol−1
- ^ ΔfG°, -79.31 kJ · mol−1
- ^ S°, 113.4 J · K−1 · mol−1
- ^ Cp°, 79.9 J · K−1 · mol−1
- ^ ΔfH°, 490.101 kJ · mol−1
- ^ ΔfH°, -251.17 kJ · mol−1
- ^ ΔfG°, -283.98 kJ · mol−1
- ^ S°, 121.50 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1