4Zn(MnO4)2 + 5e− → 4ZnO + Mn2+ + 7MnO4−
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- Reduction of zinc permanganate
- 4Zn(MnO4)2Zinc permanganate + 5e−Electron4ZnOZinc oxide + Mn2+Manganese(II) ion + 7MnO4−Permanganate ion⟶
Reduction of zinc permanganate yields zinc oxide, manganese(II) ion, and permanganate ion (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reduction of zinc permanganate
- 4Zn(MnO4)2Zinc permanganate + 5e−Electron4ZnOZinc oxide + Mn2+Manganese(II) ion + 7MnO4−Permanganate ion⟶
General equation
- Reduction of reducible species
- ReactantOxidizing agent + e− ⟶ ProductReduction product
Oxidation state of each atom
- Reduction of zinc permanganate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Zn(MnO4)2 | Zinc permanganate | 4 | Oxidizing | – |
| e− | Electron | 5 | – | Electron |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| ZnO | Zinc oxide | 4 | – | – |
| Mn2+ | Manganese(II) ion | 1 | Reduced | – |
| MnO4− | Permanganate ion | 7 | – | – |
Thermodynamic changes
Changes in aqueous solution
- Reduction of zinc permanganate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | – | – | – | 641 |
per 1 mol of | – | – | – | 160 |
per 1 mol of Electron | – | – | – | 128 |
per 1 mol of | – | – | – | 160 |
per 1 mol of Manganese(II) ion | – | – | – | 641 |
per 1 mol of Permanganate ion | – | – | – | 91.6 |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Zn(MnO4)2 (ai) | – | – | – | -251[1] |
| e− | – | – | – | – |
* (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| ZnO (cr) | -348.28[1] | -318.30[1] | 43.64[1] | 40.25[1] |
| Mn2+ (g) | 2519.69[1] | – | – | – |
| Mn2+ (ao) | -220.75[1] | -228.1[1] | -73.6[1] | 50[1] |
| MnO4− (ao) | -541.4[1] | -447.2[1] | 191.2[1] | -82.0[1] |
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ Cp°, -251. J · K−1 · mol−1
- ^ ΔfH°, -348.28 kJ · mol−1
- ^ ΔfG°, -318.30 kJ · mol−1
- ^ S°, 43.64 J · K−1 · mol−1
- ^ Cp°, 40.25 J · K−1 · mol−1
- ^ ΔfH°, 2519.69 kJ · mol−1
- ^ ΔfH°, -220.75 kJ · mol−1
- ^ ΔfG°, -228.1 kJ · mol−1
- ^ S°, -73.6 J · K−1 · mol−1
- ^ Cp°, 50. J · K−1 · mol−1
- ^ ΔfH°, -541.4 kJ · mol−1
- ^ ΔfG°, -447.2 kJ · mol−1
- ^ S°, 191.2 J · K−1 · mol−1
- ^ Cp°, -82.0 J · K−1 · mol−1